Conforms
to HazCom 2012/United States SAFETY DATA SHEET JR-100 Purple
Wash n Wax Soap
Section 1. Identification
GHS product identifier: JR-100 Purple Wash n Wax SoapOther means of identification: JR-100Product type: Liquid.Identified Uses: Exterior Wash Soaps.
Supplier's details :
Renu Chem Inc.
572 Malloy Ct
Corona Ca 92880
Tel: 951 736 8072
Toll Free: 800 721 5572
Fax: 951 344 0466
Email: [email protected] Web site: www.renuchem.com
Emergency telephone number (with hours of operation): CHEMTREC,
U.S. : 1-800-424-9300 International: +1-703-527-3887 (24/7)
Section 2. Hazards
identification
OSHA/HCS status : This material is considered
hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Classification
of the substance or mixture: SKIN
CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B
GHS label
elements
Signal word : Warning
Hazard statements : Causes skin and eye irritation.
Precautionary statements
Prevention : Wear
protective gloves. Wear eye or face protection. Wash hands
thoroughly after handling.
Response :
IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing.
Wash contaminated clothing
before reuse. If skin irritation occurs: Get medical attention. IF IN EYES:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation
persists: Get medical attention.
Storage :
Not applicable.
Disposal :
Not applicable.
Supplemental
label elements: Do not taste or swallow. Wash thoroughly after handling.
Hazards not otherwise classified: None known.
Section 3.
Composition/information on ingredients
Substance/mixture : Mixture
Other
means of identification: Not available.
CAS
number/other identifiers
CAS number : Not applicable.
Product code : JR-100.
Ingredient
name
|
%
|
CAS
number
|
Sulfonic
acids, C14-16-alkane hydroxy and C14-16-alkene, sodium salts
|
5 - 10
|
68439-57-6
|
Dodecylbenzenesulphonic
acid
|
1 - 5
|
27176-87-0
|
Alcohols, C10-16,
ethoxylated, sulfates, sodium salts
|
1 - 5
|
68585-34-2
|
Edetic acid
|
0.1 - 1
|
60-00-4
|
Sodium hydroxide
|
0.1 - 1
|
1310-73-2
|
Any concentration shown as a
range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current
knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational
exposure limits, if available, are listed in Section 8.
Section 4. First aid
measures
Description of necessary first aid measures
Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Maintain an open airway. Get medical attention if symptoms occur.
Skin contact: Flush contaminated skin with plenty of water. Continue to rinse for at least 20 minutes. Get medical attention if symptoms occur. Ingestion : Wash out mouth with water. If
material has been swallowed and the exposed person is conscious, give small
quantities of water to drink. Do not induce vomiting unless directed to do so
by medical personnel. Never give anything by mouth to an unconscious person.
Get medical attention if symptoms occur.
Most important
symptoms/effects, acute and delayed Potential acute health effects
Eye contact :
Causes
serious eye irritation.
Inhalation :
No known
significant effects or critical hazards.
Skin contact : Causes skin irritation.
Ingestion : No
known significant effects or critical hazards.
Over-exposure signs/symptomsEye contact :
Adverse symptoms may include the following: pain or irritation watering rednessInhalation: No known significant effects or critical hazards.Skin contact: Adverse symptoms may include the following: irritation rednessIngestion: No known significant effects or critical hazards.
Indication of
immediate medical attention and special treatment needed, if necessary
Notes to physician : In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under
medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken
involving any personal risk or without suitable training. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation.
See toxicological information
(Section 11)
Section 5. Fire-fighting
measures
Extinguishing media
Suitable extinguishing media: Use an extinguishing agent suitable for the surrounding fire.
Unsuitable extinguishing media: None known.
Specific
hazards arising from the chemical: No specific fire or explosion hazard.
Hazardous thermal decomposition products: Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides Sulfur oxides halogenated compounds metal oxide/oxides
Special
protective actions for fire-fighters: No special measures are required.
Special protective equipment for
fire-fighters: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6. Accidental
release measures
Personal precautions, protective equipment and emergency
procedures
For non-emergency personnel: Avoid
breathing vapor or mist. Provide adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Put on appropriate personal
protective equipment.
For emergency
responders : If specialized clothing is required to deal with the
spillage, take note of any information in Section 8 on suitable and unsuitable
materials. See also the information in "For non- emergency
personnel".
Environmental precautions: Avoid
dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).
Methods and
materials for containment and cleaning up
Spill: Stop
leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry
into sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage
with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Dispose of via a licensed waste disposal
contractor. Contaminated absorbent material may pose the same hazard as the
spilled product. Note: see Section 1 for
emergency contact information and
Section 13 for waste disposal.
Section 7. Handling and
storage
Precautions for safe
handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.
Advice on general occupational hygiene: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, including any incompatibilities: Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
Section 8. Exposure
controls/personal protection
Control parameters Occupational exposure
limits
Ingredient
name
|
Exposure
limits
|
Sodium hydroxide
|
ACGIH TLV
(United States, 6/2013).
C: 2 mg/m³
NIOSH REL (United States,
4/2013).
CEIL: 2
mg/m³
OSHA PEL (United States,
2/2013).
TWA: 2 mg/m³ 8 hours.
|
Appropriate engineering controls: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Environmental exposure controls: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.
Individual
protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Ensure that eyewash stations and safety showers are close to the workstation location.Eye/face protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Skin
protection
Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.
Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Other skin protection : Appropriate footwear and
any additional skin protection measures should be selected based on the task being performed and the risks
involved and should
be approved by a
specialist before handling this product.
Respiratory protection : Use a properly fitted, air-purifying or supplied air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Section 9. Physical and
chemical properties
Appearance Physical state: Liquid. [Thick Bodied.] Color: Purple.
Odor: Grape.
Odor threshold: Not available. pH: 8-10.5
Melting point: Not available.
Boiling point : Not available.
Flash
point: Not available.
Evaporation rate: Not available.
Flammability (solid, gas) :
Not available.
Lower
and upper explosive (flammable) limits: Not available.
Vapor
pressure: Not available.Vapor density: Not available.Relative density: Not available.Solubility: Not available.Partition coefficient: n- octanol/water: Not available.Auto-ignition
temperature: Not available.
Decomposition temperature : Not available.
Viscosity : Thick Bodied.
Section 10. Stability and
reactivity
Reactivity : No
specific test data related to reactivity available for this product or its ingredients.
Chemical stability : The product is stable.
Possibility
of hazardous reactions: Under normal conditions of
storage and use, hazardous reactions will not occur
Conditions to avoid :
No specific data.
Incompatible materials : Reactive or incompatible with the
following materials: oxidizing materials, acids and alkalis.
Slightly reactive or incompatible with the following materials:
metals.
Hazardous
decomposition products: Under
normal conditions of storage and use, hazardous decomposition products should
not be produced.
Section 11. Toxicological
information
Information on
toxicological effects Acute toxicity
Product/ingredient
name
|
Result
|
Species
|
Dose
|
Exposure
|
Dodecylbenzenesulphonic acid
|
LD50 Oral
|
Rat
|
650 mg/kg
|
-
|
Irritation/Corrosion
Product/ingredient
name
|
Result
|
Species
|
Score
|
Exposure
|
Observation
|
Dodecylbenzenesulphonic acid
|
Skin -
Severe irritant
|
Rabbit
|
-
|
0.5 mL
|
-
|
Sodium hydroxide
|
Eyes - Severe irritant
|
Monkey
|
-
|
24 hours 1%
|
-
|
|
Eyes - Mild irritant
|
Rabbit
|
-
|
400 µg
|
-
|
|
Eyes - Severe irritant
|
Rabbit
|
-
|
24 hours 50 µg
|
-
|
|
Eyes - Severe irritant
|
Rabbit
|
-
|
1%
|
-
|
|
Eyes - Severe irritant
|
Rabbit
|
-
|
0.5 minutes 1 mg
|
-
|
|
Skin - Mild irritant
|
Human
|
-
|
24 hours 2 %
|
-
|
|
Skin - Severe irritant
|
Rabbit
|
-
|
24 hours 500 mg
|
-
|
Sensitization
There is no data available.
Carcinogenicity Classification
Product/ingredient
name
|
OSHA
|
IARC
|
NTP
|
ACGIH
|
EPA
|
NIOSH
|
Edetic acid
|
-
|
-
|
-
|
-
|
-
|
None.
|
Specific target organ toxicity (single
exposure)
There is
no data available. Specific target
organ toxicity (repeated exposure) There is no data available.
Aspiration hazard
There is no data available.
Information
on the likely routes of exposure
Potential acute health effects: Dermal contact. Eye contact.
Inhalation. Ingestion.
Eye contact : Causes serious eye irritation.
Inhalation :
No known
significant effects or critical hazards.
Skin contact : Causes skin irritation.
Ingestion : No
known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact : Adverse
symptoms may include the following: pain or
irritation watering redness.
Inhalation: No known significant effects or critical hazards.Skin contact: Adverse symptoms may include the following: irritation, redness
Ingestion: No known significant effects or critical hazards.
Delayed and
immediate effects and also chronic effects from short and long term exposure Short term exposure
Potential immediate effects: No known significant effects or
critical hazards.
Potential delayed effects :
No known
significant effects or critical hazards.
Long term exposure
Potential immediate effects: No known significant effects or
critical hazards.
Potential delayed effects :
No known
significant effects or critical hazards.
Potential chronic health effects
General : No known significant effects or critical hazards.
Carcinogenicity :No known significant effects or critical hazards.
Mutagenicity :No known significant effects or critical hazards.
Teratogenicity :No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Numerical measures
of toxicity Acute
toxicity estimates
|
Route
|
ATE
value
|
Oral
|
12460.1 mg/kg
|
Section 12. Ecological
information
Toxicity
Product/ingredient
name
|
Result
|
Species
|
Exposure
|
Sulfonic acids,
C14-16-alkane hydroxy and C14-16-alkene, sodium salts
Alcohols,
C10-16, ethoxylated, sulfates, sodium salts
Edetic
acid Sodium hydroxide
|
Acute EC50 4.53 mg/L Fresh water
Acute EC50 3.43 mg/L Fresh water
Acute EC50
113000 µg/l Fresh water Acute LC50 59800 µg/l Fresh water Acute EC50 40.38
mg/L Fresh water
Acute LC50 125 ppm Fresh water
|
Crustaceans - Ceriodaphnia dubia - Neonate
Crustaceans - Ceriodaphnia dubia - Neonate
Daphnia - Daphnia magna - Neonate Fish -
Pimephales promelas Crustaceans - Ceriodaphnia dubia - Neonate
Fish - Gambusia affinis - Adult
|
48 hours
48 hours
48 hours
96 hours
48 hours
96 hours
|
Persistence and degradability
There is no data available.
Bioaccumulative
potential
Product/ingredient
name
|
LogPow
|
BCF
|
Potential
|
Edetic acid
|
-
|
1.8
|
low
|
Mobility in soil
Soil/water partition coefficient (KOC): There is no data available.
Other adverse
effects : No known significant effects
or critical hazards.
Section 13. Disposal
considerations
Disposal methods: The generation of waste should be
avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should comply
with the requirements of environmental protection and waste disposal
legislation and any regional local authority requirements. Dispose of surplus
and non-recyclable products via a licensed waste disposal contractor. Waste
should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Waste packaging should be recycled.
Incineration or landfill should only be considered when recycling is not
feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling
empty containers that have not been cleaned or rinsed out. Empty containers or
liners may retain some product residues. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
|
Section 14.
Transport information
|
|
DOT
Classification
|
IMDG
|
IATA
|
UN
number
|
Not regulated.
|
Not regulated.
|
Not regulated.
|
UN proper shipping name
|
-
|
-
|
-
|
Transport hazard class(es)
|
-
|
-
|
-
|
Packing
group
|
-
|
-
|
-
|
Environmental hazards
|
No.
|
No.
|
No.
|
Additional information
|
-
|
-
|
-
|
AERG : Not applicable.
Special precautions for user: Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according to Annex II of MARPOL 73/78 and
the IBC Code: Not available.
Section 15. Regulatory
information
U.S. Federal regulations: TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States
inventory (TSCA 8b): All components are listed or exempted.
Clean Water Act (CWA) 311:
Dodecylbenzenesulphonic acid; Edetic acid; Sodium hydroxide
Clean Air Act Section
112
(b) Hazardous Air Pollutants (HAPs): Not listed
Clean Air Act Section 602 Class I
Substances: Not listed Clean Air Act Section 602 Class II
Substances: Not listed
DEA List I Chemicals (Precursor Chemicals): Not listed
DEA List II Chemicals (Essential Chemicals): Not listed
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ :
Not applicable.
SARA 311/312
Classification : Immediate (acute) health hazard Reactive
Composition/information on ingredients
Name
|
%
|
Fire hazard
|
Sudden release of pressure
|
Reactive
|
Immediate (acute) health hazard
|
Delayed (chronic) health hazard
|
Sulfonic
acids, C14-16-alkane hydroxy and C14-16-alkene, sodium salts
Dodecylbenzenesulphonic acid
Alcohols,
C10-16, ethoxylated, sulfates, sodium salts
Edetic acid
Sodium hydroxide
|
5 - 10
1 - 5
1 - 5
0.1 - 1
0.1 - 1
|
No.
No.
No.
No.
No.
|
No.
No.
No.
No.
No.
|
No.
No.
No.
No. Yes.
|
Yes.
Yes. Yes.
Yes. Yes.
|
No.
No.
No.
No.
No.
|
State regulations
Massachusetts : The following components are
listed: Dodecylbenzenesulphonic acid; Edetic acid; Sodium hydroxide
New York : The following components are
listed: Dodecylbenzenesulphonic acid; Edetic acid; Sodium hydroxide
New Jersey : The following components are
listed: Dodecylbenzenesulphonic acid; Edetic acid; Sodium hydroxide
Pennsylvania : The following components are listed:
Dodecylbenzenesulphonic acid; Edetic acid; Sodium hydroxide
California Prop. 65
No products were found.
Section 16. Other
information
History
Date of issue mm/dd/yyyy: 04/15/2014
Version : 1
Revised Section(s) : Not applicable.
Prepared by : KMK Regulatory Services Inc.
Key to abbreviations :
ATE
= Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System
of Classification and Labelling of Chemicals IATA = International Air Transport
Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International
Convention for the Prevention of Pollution From Ships, 1973 as modified by the
Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Notice to
reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
subsidiaries, assumes any liability whatsoever for the accuracy
or completeness of the information contained herein.
Final determination of suitability of any material
is the sole responsibility of the user. All materials may present unknown
hazards and should
be used with caution.
Although certain hazards
are described herein,
we cannot guarantee that these are the only hazards that exist.
|