Conforms
to HazCom 2012/United States SAFETY DATA SHEET JR-109 Protector-Plastic, Rubber & Vinyl
Protectant
Section 1. Identification
GHS Product Identifier: JR-109 Protector-Plastic, Rubber & Vinyl Protectant Other means of identification: JR-109
Product type: Liquid. Identified uses: Rubber/vinyl/tire dressing.
Supplier's details
Renu Chem Inc.
572 Malloy Ct
Corona Ca 92880
Tel: 951 736 8072
Toll Free: 800 721 5572
Fax: 951 344 0466
Email: info@renuchem.com Web site: www.renuchem.com
Emergency telephone number (with hours of operation): CHEMTREC,
U.S. : 1-800-424-9300 International: +1-703-527-3887 (24/7)
Section 2. Hazards
identification
OSHA/HCS status : This material is considered
hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Classification
of the substance or mixture: AQUATIC HAZARD (ACUTE) - Category
3
GHS label
elements
Signal word : No signal
word. Hazard statements : Harmful to aquatic life.
Precautionary statements
Prevention : Avoid release to the environment.
Response : Not applicable.
Storage : Not applicable.
Disposal : Dispose of contents and
container in accordance with all local, regional, national and international regulations.
Hazards
not otherwise classified: None known.
Section 3.
Composition/information on ingredients
Substance/mixture : Mixture
Other
means of identification: Not available.
CAS
number/other identifiers
CAS number : Not applicable.
Product code : FR-109.
Ingredient
name
|
%
|
CAS
number
|
Siloxanes
and Silicones, di-Me
|
30 - 60
|
63148-62-9
|
Poly(oxy-1,2-ethanediyl),
α-(2-propylheptyl)-ω-hydroxy-
|
1 - 5
|
160875-66-1
|
1,3-bis(hydroxymethyl)-5,5-dimethylimidazolidine-2,4-dione
|
0.1 - 1
|
6440-58-0
|
Any concentration shown as a
range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current
knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational
exposure limits, if available, are listed in Section 8.
Section 4. First aid
measures
Description of necessary first aid measures
Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention if irritation occurs.
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Get medical attention if symptoms occur. Skin contact: Flush contaminated skin with
plenty of water. Get medical attention if symptoms occur.
Ingestion :Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. Get medical attention if symptoms occur.
Most important
symptoms/effects, acute and delayed Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : No known significant effects
or critical hazards.
Inhalation: No known significant effects or critical hazards.
Skin contact: No known significant effects or critical hazards.
Ingestion: No known significant effects or critical hazards.
Indication of immediate medical attention and special
treatment needed, if necessary
Notes to physician : In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under
medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No special protection is required.
See toxicological information
(Section 11)
Section 5. Fire-fighting
measures
Extinguishing media
Suitable extinguishing media: Use an extinguishing agent suitable for the surrounding fire.
Unsuitable extinguishing media: None known.
Specific
hazards arising from the chemical: This material is harmful to aquatic life. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous thermal decomposition products: Decomposition products may include the following materials: carbon dioxide carbon monoxide
nitrogen oxides
Special
protective actions for fire-fighters: No special measures are required.
Special protective equipment for
fire-fighters: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6. Accidental
release measures
Personal precautions, protective equipment and emergency
procedures
For non-emergency personnel: Avoid
breathing vapor or mist. Provide adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Put on appropriate personal
protective equipment.
For emergency
responders : If specialized clothing is required to deal with the
spillage, take note of any information in Section 8 on suitable and unsuitable
materials. See also the information in "For non- emergency
personnel".
Environmental precautions: Avoid
dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air). Water polluting
material. May be harmful to the environment if released in large quantities.
Methods and
materials for containment and cleaning up
Spill: Stop
leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry
into sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage
with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Dispose of via a licensed waste disposal
contractor. Contaminated absorbent material may pose the same hazard as the
spilled product. Note: see Section 1 for
emergency contact information and
Section 13 for waste disposal.
Section 7. Handling and
storage
Precautions for safe
handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.
Advice on general occupational hygiene: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, including any incompatibilities: Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
Section 8. Exposure
controls/personal protection
Control parameters Occupational exposure
limits None.
Appropriate engineering controls: Good general ventilation should be sufficient to control worker exposure to airborne contaminants.
Environmental exposure controls: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Ensure that eyewash stations and safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields.
Skin protection
Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.
Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Other skin protection : Appropriate footwear and
any additional skin protection measures should be selected based on the task being performed and the risks
involved and should
be approved by a
specialist before handling this product.
Respiratory protection :Use a properly fitted, air-purifying or supplied air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Section 9. Physical and
chemical properties
Appearance Physical state: Liquid. [Thin Bodied.]Color: White.Odor: Banana. Odor threshold: Not available. pH: 7-8.5 Melting point: Not available.
Boiling point : Not available.
Flash
point: Not available.
Evaporation rate: Not available.
Flammability (solid,
gas) : Not available.
Lower
and upper explosive (flammable) limits: Not available.
Vapor
pressure: Not available.
Vapor density: Not available.
Relative density: Not available.
Solubility: Not available.
Partition coefficient: n- octanol/water: Not available.
Auto-ignition
temperature: Not available.
Decomposition temperature : Not available. Viscosity: Thin Bodied.
Section 10. Stability and
reactivity
Reactivity : No
specific test data related to reactivity available for this product or its ingredients.
Chemical stability : The product is stable.
Possibility
of hazardous reactions: Under normal conditions of
storage and use, hazardous reactions will not occur.
Conditions to avoid :
No specific data.
Incompatible materials : Reactive or incompatible with the following
materials: oxidizing materials.
Hazardous
decomposition products: Under
normal conditions of storage and use, hazardous decomposition products should
not be produced.
Section 11. Toxicological
information
Information on
toxicological effects Acute toxicity
Product/ingredient
name
|
Result
|
Species
|
Dose
|
Exposure
|
Siloxanes and Silicones, di-Me
|
LD50 Oral
|
Rat
|
>2000
mg/kg
|
-
|
1,3-bis(hydroxymethyl)-5,
|
LD50 Oral
|
Rat
|
2 g/kg
|
-
|
5-dimethylimidazolidine-2,4-dione
|
|
|
|
|
Irritation/Corrosion
Product/ingredient
name
|
Result
|
Species
|
Score
|
Exposure
|
Observation
|
Siloxanes and Silicones, di-Me
1,3-bis(hydroxymethyl)-5,
5-dimethylimidazolidine-2,4-dione
|
Eyes - Mild
irritant Skin - Mild irritant Eyes - Mild irritant Skin - Moderate irritant
|
Rabbit Rabbit Rabbit Rabbit
|
-
-
-
-
|
1 hours 100
mg
24 hours 500 µL
24 hours 100 µL
24 hours 2 mg
|
-
-
-
-
|
Sensitization
There is no data available.
Carcinogenicity
There is
no data available. Specific target
organ toxicity (single exposure) There
is no data available.
Specific target
organ toxicity (repeated exposure)
There is no data available.
Aspiration hazard
There is no data available.
Information
on the likely routes of exposure: Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Symptoms
related to the physical, chemical
and toxicological characteristics
Eye contact : No known significant effects or
critical hazards.
Inhalation: No known significant effects or critical hazards.
Skin contact: No known significant effects or critical hazards.
Ingestion: No known significant effects or critical hazards.
Delayed and
immediate effects and also chronic effects from short and long term exposure Short term exposure
Potential immediate effects: No
known significant effects or critical hazards.
Potential delayed effects :
No known
significant effects or critical hazards.
Long term exposure
Potential immediate effects: No known significant effects or
critical hazards.
Potential delayed effects :
No known
significant effects or critical hazards.
Potential chronic health effects
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Numerical measures of toxicity Acute toxicity
estimates
Route
|
ATE
value
|
Oral
|
12195.1 mg/kg
|
Section 12. Ecological
information
Toxicity
Product/ingredient
name
|
Result
|
Species
|
Exposure
|
Siloxanes and Silicones, di-Me
1,3-bis(hydroxymethyl)-5,
5-dimethylimidazolidine-2,4-dione
|
Acute LC50
44.5 ppm Fresh water
Acute LC50 3160 to 4150
µg/l Fresh water Acute LC50 173 to 212 ppm Fresh water
|
Daphnia -
Daphnia magna - Instar Fish - Ictalurus punctatus
Fish - Lepomis macrochirus
|
48 hours
96 hours
96 hours
|
Persistence and degradability
There is no data available.
Bioaccumulative
potential
There is no data available.
Mobility in
soil
Soil/water partition coefficient (KOC): There is no data available.
Other adverse effects :
No known
significant effects or critical hazards.
Section 13. Disposal
considerations
Disposal
methods: The generation of waste should be
avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should comply
with the requirements of environmental protection and waste disposal
legislation and any regional local authority requirements. Dispose of surplus
and non-recyclable products via a licensed waste disposal contractor. Waste
should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Waste packaging should be recycled.
Incineration or landfill should only be considered when recycling is not
feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling
empty containers that have not been cleaned or rinsed out. Empty containers or
liners may retain some product residues. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
Section 14. Transport Information
|
DOT
Classification
|
IMDG
|
IATA
|
UN
number
|
Not regulated.
|
Not regulated.
|
Not regulated.
|
UN proper shipping name
|
-
|
-
|
-
|
Transport hazard class(es)
|
-
|
-
|
-
|
Packing
group
|
-
|
-
|
-
|
Environmental hazards
|
No.
|
No.
|
No.
|
Additional information
|
-
|
-
|
-
|
AERG : Not applicable.
Special precautions for user: Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according to Annex II of MARPOL 73/78 and
the IBC Code: Not available.
Section 15. Regulatory
information
U.S. Federal regulations: TSCA 4(a) final test rules: Acetaldehyde
TSCA 8(a) PAIR: Siloxanes and Silicones, di-Me;
Acetaldehyde TSCA 8(a) CDR
Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): Not determined.
Clean Water Act (CWA) 311: Acetaldehyde
Clean Air Act Section
112
(b) Hazardous Air Pollutants (HAPs): Not listed
Clean Air Act Section 602 Class I
Substances: Not listed
Clean Air Act Section 602 Class II
Substances: Not listed
DEA List I Chemicals (Precursor Chemicals): Not listed
DEA List II Chemicals (Essential Chemicals): Not listed
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ :
Not applicable.
SARA 311/312
Classification :
Immediate
(acute) health hazard
Composition/information on ingredients
Name
|
%
|
Fire hazard
|
Sudden release of pressure
|
Reactive
|
Immediate (acute) health hazard
|
Delayed (chronic) health hazard
|
Poly(oxy-1,2-ethanediyl),
α-(2-propylheptyl)-ω-
|
1 - 5
|
No.
|
No.
|
No.
|
Yes.
|
No.
|
hydroxy-
|
|
|
|
|
|
|
1,3-bis(hydroxymethyl)-5,
|
0.1 - 1
|
No.
|
No.
|
No.
|
Yes.
|
No.
|
5-dimethylimidazolidine-2,4-dione
|
|
|
|
|
|
|
State regulations Massachusetts :The following components are
listed: Glycerol
New York : None of the components are listed.
New Jersey : The following components are listed: Glycerol
Pennsylvania : The following components are listed: Glycerol
California Prop. 65
WARNING: This product contains less than 0.1% of a chemical known
to the State of California to cause cancer.
Ingredient
name
|
Cancer
|
Reproductive
|
No significant risk level
|
Maximum acceptable dosage level
|
Acetaldehyde
|
Yes.
|
No.
|
90 µg/day (inhalation)
|
No.
|
Section 16. Other
information
History
Date of issue mm/dd/yyyy: 04/15/2014
Version : 1
Revised Section(s) : Not applicable.
Prepared by : KMK Regulatory Services Inc.
Key to abbreviations :
ATE
= Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System
of Classification and Labelling of Chemicals IATA = International Air Transport
Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International
Convention for the Prevention of Pollution From Ships, 1973 as modified by the
Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
subsidiaries, assumes any liability whatsoever for the accuracy
or completeness of the information contained herein.
Final determination of suitability of any material
is the sole responsibility of the user. All materials may present unknown
hazards and should
be used with caution.
Although certain hazards
are described herein,
we cannot guarantee that these are the only hazards that exist.
|