Conforms to HazCom 2012/United States SAFETY DATA SHEET JR-105 RED - Waterspot Remover
Section 1. Identification GHS product
identifier: JR-105 Red Water Spot Remover
Other means of identification: JR-105. Product type: Liquid. Identified uses: Not available.
Renu Chem Inc.
572 Malloy Ct
Corona Ca 92880
Tel: 951 736 8072
Toll Free: 800 721 5572 Fax: 951 344 0466
Emergency telephone
number (with hours of operation): CHEMTREC,
U.S. : 1-800-424-9300 International: +1-703-527-3887 (24/7)
Section 2. Hazards
identification
OSHA/HCS status :
This material is considered hazardous by the OSHA Hazard Communication
Standard (29 CFR 1910.1200). Classification of the substance or mixture: ACUTE TOXICITY (oral) -
Category 4
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
GHS label elements
Signal word : Warning
Hazard statements : Harmful if swallowed.
Causes
serious eye irritation. Causes skin irritation.
Precautionary statements
Prevention: Wear
protective gloves. Wear eye or face protection. Do not eat, drink
or smoke when using this product. Wash hands
thoroughly after handling.
Response:
IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell.
Rinse mouth. IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing. Wash contaminated clothing before reuse. If skin
irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation
persists: Get medical attention.
Storage :
Not applicable.
Disposal: Dispose of contents and
container in accordance with all local, regional, national and international regulations.
Hazards
not otherwise classified: None known.
Section 3.
Composition/information on ingredients
Substance/mixture: Mixture
Other
means of identification: Not available.
CAS number/other identifiers
CAS number : Not applicable.
Product code : JR-105.
Ingredient
name
|
%
|
CAS
number
|
Ammonium bifluoride
|
1 - 15
|
1341-49-7
|
Sodium
octane-1-sulphonate monohydrate
|
1 - 15
|
5324-84-5
|
Sulfuric
acid
|
0.1 - 1
|
7664-93-9
|
Any concentration shown as a range
is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within
the current knowledge of the supplier
and in the concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational
exposure limits, if available, are listed in Section 8.
Section 4. First aid
measures
Description of necessary first aid measures
Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention.
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Skin contact: Wash contaminated skin with soap and water. Continue to rinse for at least 20 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion: Wash out mouth
with water. If material has been swallowed and the exposed person is conscious,
give small quantities of water to drink. Stop if the exposed person feels sick
as vomiting may be dangerous. Do not induce vomiting unless directed to do so
by medical personnel. If vomiting occurs, the head should be kept low so that
vomit does not enter the lungs. Never give anything by mouth to an unconscious
person. Get medical attention if symptoms occur.
Most important
symptoms/effects, acute and delayed Potential acute health effects
Eye contact :
Causes
serious eye irritation.
Inhalation :
No known
significant effects or critical hazards.
Skin contact : Causes skin irritation.
Ingestion : Harmful
if swallowed. Irritating to mouth, throat and
stomach.
Over-exposure signs/symptoms
Eye contact :
Adverse symptoms may include the following: pain or irritation
watering redness
Inhalation: No known significant effects or critical hazards.
Skin contact: Adverse symptoms may include the following: irritation, rednessIngestion: No known significant effects or critical hazards.
Indication of immediate medical attention and special
treatment needed, if necessaryNotes to physician: In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under
medical surveillance for 48 hours.Specific treatments : No specific treatment.Protection of first-aiders : No action shall be taken
involving any personal risk or without suitable training. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation.
See toxicological information
(Section 11)
Section 5. Fire-fighting
measures
Extinguishing media
Suitable extinguishing media: Use an extinguishing agent suitable for the surrounding fire.
Unsuitable extinguishing media: None known.
Specific
hazards arising from the chemical: No specific fire or explosion hazard.
Hazardous thermal decomposition products: Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides Sulfur oxides halogenated compounds metal oxide/oxides
Special
protective actions for fire-fighters: No special measures are required.
Special protective equipment for
fire-fighters: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6. Accidental
release measures
Personal precautions, protective equipment and emergency
procedures
For non-emergency personnel: Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
For emergency
responders : If specialized clothing is required to deal with the
spillage, take note of any information in Section 8 on suitable and unsuitable
materials. See also the information in "For non- emergency
personnel".
Environmental
precautions: Avoid
dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
Spill: Stop
leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry
into sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage
with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). The spilled material may be neutralized with
sodium carbonate, sodium bicarbonate or sodium hydroxide. Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose
the same hazard as the spilled product. Note: see Section 1 for emergency
contact information and Section 13 for waste
disposal.
Section 7. Handling and
storage
Precautions
for safe handling Protective measures: Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Keep away from alkalis. Empty containers retain product residue and can be hazardous. Do not reuse container.
Advice on general occupational hygiene: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures.Conditions for safe storage including any incompatibilities:Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Separate from alkalis. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
Section 8. Exposure
controls/personal protection
Control parameters Occupational exposure
limits
|
Ingredient
name
|
Exposure
limits
|
Ammonium bifluoride
Sulfuric acid
|
OSHA PEL Z2 (United
States, 2/2013). TWA: 2.5
mg/m³ 8 hours. Form:
Dust ACGIH TLV
(United
States, 6/2013).
TWA: 2.5 mg/m³, (as F) 8 hours. OSHA PEL
(United States, 2/2013). TWA: 2.5 mg/m³, (as F) 8 hours.
NIOSH REL
(United States, 4/2013).
TWA: 1 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1 mg/m³ 8 hours.
ACGIH TLV (United States, 6/2013).
TWA: 0.2 mg/m³ 8 hours. Form: thoracic
fraction
|
Appropriate engineering controls: Good general ventilation should be sufficient to control worker exposure to airborne contaminants.
Environmental exposure controls: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.
Individual
protection measures Hygiene measures:Wash hands, forearms and face
thoroughly after handling chemical products, before eating, smoking and using
the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.Skin
protection Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.
Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Other skin protection : Appropriate footwear and
any additional skin protection measures should be selected based on the task being performed and the risks
involved and should
be approved by a
specialist before handling this product.
Respiratory protection : Use a properly fitted, air-purifying or supplied air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Section 9. Physical and
chemical properties
Appearance Physical state: Med Bodied .Color: Pink.
Odor: Bubble Gum. Odor threshold: Not available. pH: 1.5-3
Melting point: Not available.
Boiling point: Not available.
Flash
point: Not available. Evaporation rate: Not available.
Flammability (solid,
gas): Not available.
Lower
and upper explosive (flammable) limits: Not available.
Vapor
pressure: Not available.Vapor density: Not available.Relative density: Not available.Solubility: Not available.
Partition coefficient: n- octanol/water: Not available.
Auto-ignition
temperature: Not available.
Decomposition temperature : Not available.
Viscosity: Med Bodied
Section 10. Stability and
reactivity
Reactivity : No
specific test data related to reactivity available for this product or its ingredients.
Chemical stability : The product is stable.
Possibility
of hazardous reactions: Under normal conditions of
storage and use, hazardous reactions will not occur.
Conditions to avoid :
No specific data.
Incompatible materials :Reactive or incompatible with the
following materials: oxidizing materials, reducing materials, organic
materials, alkalis and moisture.
Hazardous
decomposition products: Under
normal conditions of storage and use, hazardous decomposition products should
not be produced.
Section 11. Toxicological
information
Information on
toxicological effects Acute toxicity
Product/ingredient
name
|
Result
|
Species
|
Dose
|
Exposure
|
Sulfuric acid
|
LD50 Oral
|
Rat
|
2140 mg/kg
|
-
|
Irritation/Corrosion
Product/ingredient
name
|
Result
|
Species
|
Score
|
Exposure
|
Observation
|
Sulfuric
acid
|
Eyes -
Severe
irritant Eyes -
Severe irritant
|
Rabbit
Rabbit
|
-
-
|
250 µg
0.5
minutes
5 mg
|
-
-
|
Sensitization
There is no data available.
Carcinogenicity
Classification
Product/ingredient
name
|
OSHA
|
IARC
|
NTP
|
ACGIH
|
EPA
|
NIOSH
|
Ammonium bifluoride
Sulfuric acid
|
-
-
|
3
1
|
-
Known to be
a human carcinogen.
|
A4 A2
|
-
-
|
-
-
|
Specific target organ toxicity (single exposure)
Name
|
Category
|
Route of exposure
|
Target
organs
|
Sodium
octane-1-sulphonate monohydrate
|
Category 3
|
Not applicable.
|
Respiratory tract irritation
|
Specific target organ toxicity (repeated
exposure)
There is no data available.
Aspiration hazard
There is no data available.
Information
on the likely routes of exposure: Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation :
No known
significant effects or critical hazards.
Skin contact : Causes skin irritation.
Ingestion : Harmful
if swallowed. Irritating to mouth, throat and
stomach.
Symptoms related to the physical,
chemical and toxicological characteristics
Eye contact : Adverse
symptoms may include the following: pain or
irritation watering redness
Inhalation: No known significant effects or critical hazards. Skin contact: Adverse symptoms may include the following: irritation, redness
Ingestion: No known significant effects or
critical hazards.
Delayed and
immediate effects and also chronic effects from short and long term exposure Short term exposure
Potential immediate effects: No known significant effects or
critical hazards.
Potential delayed effects :
No known
significant effects or critical hazards.
Long term exposure
Potential immediate effects: No known significant effects or
critical hazards.
Potential delayed effects :
No known
significant effects or critical hazards.
Potential chronic health effects
General :No known significant effects or critical hazards.
Carcinogenicity :No known significant effects or critical hazards.
Mutagenicity :No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects :
No
known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Numerical measures of toxicity Acute toxicity
estimates
Route
|
ATE
value
|
Oral
|
1981.5 mg/kg
|
Section 12. Ecological
information
Toxicity
Product/ingredient
name
|
Result
|
Species
|
Exposure
|
Sulfuric
acid
|
Acute LC50
42500 µg/L
Marine water Acute LC50
42 ppm Fresh water
|
Crustaceans
- Pandalus
montagui - Adult Fish -
Gambusia affinis - Adult
|
48 hours
96 hours
|
Persistence and degradability
There is no data available.
Bioaccumulative potential
There is no data available.
Mobility in soil
Soil/water partition coefficient (KOC): There is no data available.
Other adverse
effects : No known significant effects
or critical hazards.
Section 13. Disposal
considerations
Disposal methods: The generation of waste should be
avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and
non-recyclable products via a licensed waste disposal contractor. Waste should
not be disposed of untreated to the sewer unless fully compliant with the
requirements of all authorities with jurisdiction. Waste packaging should be recycled.
Incineration or landfill should only be considered when recycling is not
feasible. This material and its container must be disposed of in a safe way. Care
should be taken when handling empty containers that have not been cleaned or
rinsed out. Empty containers or liners may retain some product residues. Avoid
dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers.
Section 14.
Transport information
|
|
DOT
Classification
|
IMDG
|
IATA
|
UN
number
|
Not regulated.
|
Not regulated.
|
Not regulated.
|
UN proper shipping name
|
-
|
-
|
-
|
Transport hazard class(es)
|
-
|
-
|
-
|
Packing
group
|
-
|
-
|
-
|
Environmental hazards
|
No.
|
No.
|
No.
|
Additional information
|
-
|
-
|
-
|
AERG : Not applicable.
Special precautions for user: Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according to Annex II of MARPOL 73/78 and
the IBC Code: Not available.
Section 15. Regulatory
information
U.S. Federal regulations: TSCA 8(a) CDR Exempt/Partial
exemption:
Not determined
Commerce
control list precursor: Ammonium bifluoride
United States inventory
(TSCA 8b):
All components are listed or exempted.
Clean Water Act (CWA) 311: Ammonium bifluoride;
Sulfuric acid
Clean Air Act Section 112
(b) Hazardous Air Pollutants (HAPs): Not listed
Clean Air Act Section 602 Class I
Substances: Not listed
Clean Air Act Section 602 Class II
Substances: Not listed
DEA List I Chemicals (Precursor Chemicals): Not listed
DEA List II Chemicals (Essential Chemicals): Not listed
SARA 302/304
Composition/information on ingredients
Section 15.
Regulatory information
|
|
|
Name
|
%
|
EHS
|
SARA
302 TPQ
|
SARA
304 RQ
|
(lbs)
|
(gallons)
|
(lbs)
|
(gallons)
|
Sulfuric acid
|
0.1 - 1
|
Yes.
|
1000
|
66.3
|
1000
|
66.3
|
|
|
|
|
|
|
|
|
|
SARA 304 RQ :
100000 lbs
/ 45400 kg
SARA 311/312
Classification :
Immediate
(acute) health hazard
Composition/information on ingredients
Name
|
%
|
Fire hazard
|
Sudden release of pressure
|
Reactive
|
Immediate (acute) health hazard
|
Delayed (chronic)
health hazard
|
Ammonium bifluoride
|
1 - 15
|
No.
|
No.
|
No.
|
Yes.
|
No.
|
Sodium octane-1-sulphonate
monohydrate
|
1 - 15
|
No.
|
No.
|
No.
|
Yes.
|
No.
|
Sulfuric
acid
|
0.1 - 1
|
No.
|
No.
|
No.
|
Yes.
|
No.
|
SARA 313
|
Product
name
|
CAS
number
|
%
|
Form R - Reporting requirements
|
Ammonium
bifluoride Sulfuric acid
|
1341-49-7
7664-93-9
|
1 - 15
0.1 - 1
|
Supplier
notification
|
Ammonium
bifluoride Sulfuric acid
|
1341-49-7
7664-93-9
|
1 - 15
0.1 - 1
|
SARA 313 notifications must not
be detached from the SDS and any copying and redistribution of the SDS shall
include copying and redistribution of the notice attached to copies of the SDS
subsequently redistributed.
State regulations
Massachusetts : The following
components are listed: Ammonium bifluoride; Sulfuric acid
New
York : The
following components are listed: Ammonium bifluoride; Sulfuric acid
New Jersey :
The following components are listed: Ammonium bifluoride; Sulfuric
acid
Pennsylvania : The following components are
listed: Ammonium bifluoride; Sulfuric acid California
Prop. 65
WARNING: This product contains a chemical known to the State of
California to cause cancer.
Ingredient
name
|
Cancer
|
Reproductive
|
No significant risk level
|
Maximum acceptable dosage level
|
Risk of cancer depends on duration and level
of exposure to the sulfuric acid mist.
|
Yes.
|
No.
|
No.
|
No.
|
Section 16. Other
information
History
Date of issue mm/dd/yyyy: 08/15/2014
Version : 1
Revised Section(s) : Not applicable.
Prepared by : KMK Regulatory Services Inc.
Key to abbreviations :
ATE
= Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System
of Classification and Labelling of Chemicals IATA = International Air Transport
Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International
Convention for the Prevention of Pollution From Ships, 1973 as modified by the
Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
subsidiaries, assumes any liability whatsoever for the accuracy
or completeness of the information contained herein.
Final determination of suitability of any material
is the sole responsibility of the user.
All materials may present
unknown hazards and should be used
with caution. Although
certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist.
|