Home > SDS - Safety Data Sheets > RED WATERSPOT REMOVER
Conforms to HazCom 2012/United States
SAFETY DATA SHEET
JR-105 RED - Waterspot Remover

Section 1. Identification
GHS product identifier: JR-105 Red Water Spot Remover

Other means of identification: JR-105.

Product type: Liquid.
Identified uses: Not available.

Supplier's details:

Renu Chem Inc.

572 Malloy Ct

Corona Ca 92880

Tel: 951 736 8072

Toll Free: 800 721 5572
Fax: 951 344 0466


Emergency telephone number (with hours of operation): CHEMTREC, U.S. : 1-800-424-9300 International: +1-703-527-3887 (24/7)


Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Classification of the substance or mixture: ACUTE TOXICITY (oral) - Category 4

SKIN CORROSION/IRRITATION - Category 2

SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2


GHS label elements

Signal word : Warning

Hazard statements : Harmful if swallowed.

Causes serious eye irritation. Causes skin irritation.

Precautionary statements

Prevention: Wear protective gloves. Wear eye or face protection. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling.

Response: IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage : Not applicable.

Disposal: Dispose of contents and container in accordance with all local, regional, national and international regulations.


Hazards not otherwise classified: None known.


Section 3. Composition/information on ingredients

Substance/mixture: Mixture


Other means of identification: Not available.

CAS number/other identifiers

CAS number : Not applicable.

Product code : JR-105.

Ingredient name

%

CAS number

Ammonium bifluoride

1 - 15

1341-49-7

Sodium octane-1-sulphonate monohydrate

1 - 15

5324-84-5

Sulfuric acid

0.1 - 1

7664-93-9

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.


Section 4. First aid measures

Description of necessary first aid measures


Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention.

Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.

Skin contact: Wash contaminated skin with soap and water. Continue to rinse for at least 20 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Ingestion: Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. Get medical attention if symptoms occur.

Most important symptoms/effects, acute and delayed Potential acute health effects

Eye contact : Causes serious eye irritation.

Inhalation : No known significant effects or critical hazards.

Skin contact : Causes skin irritation.

Ingestion : Harmful if swallowed. Irritating to mouth, throat and stomach.

Over-exposure signs/symptoms

Eye contact : Adverse symptoms may include the following: pain or irritation

watering redness


Inhalation: No known significant effects or critical hazards.

Skin contact: Adverse symptoms may include the following: irritation, redness

Ingestion: No known significant effects or critical hazards.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician: In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Specific treatments : No specific treatment.

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)


Section 5. Fire-fighting measures

Extinguishing media

Suitable extinguishing media: Use an extinguishing agent suitable for the surrounding fire.

Unsuitable extinguishing media: None known.

Specific hazards arising from the chemical: No specific fire or explosion hazard.

Hazardous thermal decomposition products: Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides Sulfur oxides halogenated compounds metal oxide/oxides


Special protective actions for fire-fighters: No special measures are required.

Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.


Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

For non-emergency personnel: Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel".

Environmental precautions: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).


Methods and materials for containment and cleaning up


Spill: Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). The spilled material may be neutralized with sodium carbonate, sodium bicarbonate or sodium hydroxide. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.



Section 7. Handling and storage


Precautions for safe handling

Protective measures: Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Keep away from alkalis. Empty containers retain product residue and can be hazardous. Do not reuse container.


Advice on general occupational hygiene: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures.


Conditions for safe storage including any incompatibilities:Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Separate from alkalis. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.


Section 8. Exposure controls/personal protection

Control parameters

Occupational exposure limits


Ingredient name

Exposure limits

Ammonium bifluoride

Sulfuric acid

OSHA PEL Z2 (United

States, 2/2013). TWA: 2.5

mg/m³ 8 hours. Form:

Dust ACGIH TLV (United

States, 6/2013).

TWA: 2.5 mg/m³, (as F) 8 hours. OSHA PEL

(United States, 2/2013). TWA: 2.5

mg/m³, (as F) 8 hours.

NIOSH REL (United States, 4/2013).

TWA: 1 mg/m³ 10 hours.

OSHA PEL (United States, 2/2013).

TWA: 1 mg/m³ 8 hours.

ACGIH TLV (United States, 6/2013).

TWA: 0.2 mg/m³ 8 hours. Form: thoracic fraction


Appropriate engineering controls: Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Environmental exposure controls: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.



Individual protection measures

Hygiene measures:Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.


Eye/face protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Skin protection

Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.

Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.


Respiratory protection : Use a properly fitted, air-purifying or supplied air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.


Section 9. Physical and chemical properties


Appearance

Physical state: Med Bodied .

Color: Pink.

Odor: Bubble Gum.

Odor threshold: Not available.

pH: 1.5-3

Melting point: Not available.

Boiling point: Not available.

Flash point: Not available.

Evaporation rate: Not available.

Flammability (solid, gas): Not available.

Lower and upper explosive (flammable) limits: Not available.

Vapor pressure: Not available.

Vapor density: Not available.

Relative density: Not available.

Solubility: Not available.

Partition coefficient: n- octanol/water: Not available.

Auto-ignition temperature: Not available.

Decomposition temperature : Not available.

Viscosity: Med Bodied


Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.


Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.


Conditions to avoid : No specific data.


Incompatible materials :Reactive or incompatible with the following materials: oxidizing materials, reducing materials, organic materials, alkalis and moisture.



Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should not be produced.


Section 11. Toxicological information

Information on toxicological effects Acute toxicity

Product/ingredient name

Result

Species

Dose

Exposure

Sulfuric acid

LD50 Oral

Rat

2140 mg/kg

-

Irritation/Corrosion

Product/ingredient name

Result

Species

Score

Exposure

Observation

Sulfuric acid

Eyes - Severe

irritant Eyes -

Severe irritant

Rabbit Rabbit

-

-

250 µg

0.5

minutes 5 mg

-

-

Sensitization

There is no data available.

Carcinogenicity

Classification

Product/ingredient name

OSHA

IARC

NTP

ACGIH

EPA

NIOSH

Ammonium bifluoride Sulfuric acid

-

-

3

1

-

Known to be a human carcinogen.

A4 A2

-

-

-

-

Specific target organ toxicity (single exposure)

Name

Category

Route of exposure

Target organs

Sodium octane-1-sulphonate monohydrate

Category 3

Not applicable.

Respiratory tract irritation

Specific target organ toxicity (repeated exposure)

There is no data available.

Aspiration hazard

There is no data available.


Information on the likely routes of exposure: Dermal contact. Eye contact. Inhalation. Ingestion.


Potential acute health effects

Eye contact : Causes serious eye irritation.

Inhalation : No known significant effects or critical hazards.

Skin contact : Causes skin irritation.

Ingestion : Harmful if swallowed. Irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact :
Adverse symptoms may include the following:
pain or irritation watering redness

Inhalation: No known significant effects or critical hazards.

Skin contact: Adverse symptoms may include the following: irritation, redness

Ingestion: No known significant effects or critical hazards.


Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure


Potential immediate effects: No known significant effects or critical hazards.


Potential delayed effects : No known significant effects or critical hazards.


Long term exposure


Potential immediate effects: No known significant effects or critical hazards.


Potential delayed effects : No known significant effects or critical hazards.


Potential chronic health effects

General :No known significant effects or critical hazards.

Carcinogenicity :No known significant effects or critical hazards.

Mutagenicity :No known significant effects or critical hazards.

Teratogenicity : No known significant effects or critical hazards.

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity Acute toxicity estimates

Route

ATE value

Oral

1981.5 mg/kg


Section 12. Ecological information

Toxicity

Product/ingredient name

Result

Species

Exposure

Sulfuric acid

Acute LC50 42500 µg/L

Marine water Acute LC50

42 ppm Fresh water

Crustaceans - Pandalus

montagui - Adult Fish -

Gambusia affinis - Adult

48 hours

96 hours

Persistence and degradability

There is no data available.

Bioaccumulative potential

There is no data available.


Mobility in soil

Soil/water partition coefficient (KOC): There is no data available.


Other adverse effects : No known significant effects or critical hazards.


Section 13. Disposal considerations


Disposal methods: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.


Section 14. Transport information

DOT Classification

IMDG

IATA

UN number

Not regulated.

Not regulated.

Not regulated.

UN proper shipping name

-

-

-

Transport hazard class(es)

-

-

-

Packing group

-

-

-

Environmental hazards

No.

No.

No.

Additional information

-

-

-

AERG : Not applicable.


Special precautions for user: Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not available.



Section 15. Regulatory information


U.S. Federal regulations: TSCA 8(a) CDR Exempt/Partial exemption: Not determined

Commerce control list precursor: Ammonium bifluoride

United States inventory (TSCA 8b): All components are listed or exempted.

Clean Water Act (CWA) 311: Ammonium bifluoride; Sulfuric acid



Clean Air Act Section 112

(b) Hazardous Air Pollutants (HAPs): Not listed

Clean Air Act Section 602 Class I Substances: Not listed

Clean Air Act Section 602 Class II Substances: Not listed

DEA List I Chemicals (Precursor Chemicals): Not listed

DEA List II Chemicals (Essential Chemicals): Not listed

SARA 302/304


Composition/information on ingredients



Section 15. Regulatory information

Name

%

EHS

SARA 302 TPQ

SARA 304 RQ

(lbs)

(gallons)

(lbs)

(gallons)

Sulfuric acid

0.1 - 1

Yes.

1000

66.3

1000

66.3

SARA 304 RQ : 100000 lbs / 45400 kg

SARA 311/312

Classification : Immediate (acute) health hazard

Composition/information on ingredients

Name

%

Fire hazard

Sudden release of pressure

Reactive

Immediate (acute) health hazard

Delayed (chronic) health hazard

Ammonium bifluoride

1 - 15

No.

No.

No.

Yes.

No.

Sodium octane-1-sulphonate

monohydrate

1 - 15

No.

No.

No.

Yes.

No.

Sulfuric acid

0.1 - 1

No.

No.

No.

Yes.

No.

SARA 313

Product name

CAS number

%

Form R - Reporting requirements

Ammonium

bifluoride Sulfuric acid

1341-49-7

7664-93-9

1 - 15

0.1 - 1

Supplier notification

Ammonium

bifluoride Sulfuric acid

1341-49-7

7664-93-9

1 - 15

0.1 - 1

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.

State regulations

Massachusetts : The following components are listed: Ammonium bifluoride; Sulfuric acid


New York :
The following components are listed: Ammonium bifluoride; Sulfuric acid

New Jersey : The following components are listed: Ammonium bifluoride; Sulfuric acid

Pennsylvania : The following components are listed: Ammonium bifluoride; Sulfuric acid California

Prop. 65

WARNING: This product contains a chemical known to the State of California to cause cancer.

Ingredient name

Cancer

Reproductive

No significant risk level

Maximum acceptable dosage level

Risk of cancer depends on duration and level of exposure to the sulfuric acid mist.

Yes.

No.

No.

No.


Section 16. Other information


History

Date of issue mm/dd/yyyy: 08/15/2014


Version : 1

Revised Section(s) : Not applicable.

Prepared by : KMK Regulatory Services Inc.

Key to abbreviations : ATE = Acute Toxicity Estimate

BCF = Bioconcentration Factor

GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association

IBC = Intermediate Bulk Container

IMDG = International Maritime Dangerous Goods

LogPow = logarithm of the octanol/water partition coefficient

MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)

UN = United Nations

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.