Conforms
to HazCom 2012/United States SAFETY DATA SHEET JR-103 Clear- Glass Cleaner
Section 1. Identification
GHS product identifier: JR-103 Clear-Glass CleanerOther means of identification: JR-103.Product type: Liquid.Identified Uses: Glass cleaner.Supplier's details :
Emergency telephone number (with hours of operation): CHEMTREC,
U.S. : 1-800-424-9300 International: +1-703-527-3887 (24/7)
Section 2. Hazards
identification
OSHA/HCS status : This material is considered
hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Classification
of the substance or mixture: SERIOUS EYE
DAMAGE/ EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
GHS label
elements
Signal word : Warning
Hazard statements : Flammable liquid and vapor.
Causes serious eye irritation.
May cause drowsiness and dizziness.
Precautionary statements
Prevention : Wear
protective gloves. Wear eye or face protection. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Use explosion- proof electrical, ventilating, lighting and all
material-handling equipment. Use only non- sparking tools. Take precautionary
measures against static discharge. Keep container tightly closed. Use only
outdoors or in a well-ventilated area. Avoid breathing vapor.
Wash hands thoroughly after handling.
Response : IF
INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing. Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin
with water or shower. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If
eye irritation persists: Get medical attention.
Storage : Store
locked up. Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and
container in accordance with all local, regional, national and international regulations.
Hazards
not otherwise classified: None known.
Section 3.
Composition/information on ingredients
Substance/mixture : Mixture
Other
means of identification: Not available.
CAS
number/other identifiers
CAS number : Not applicable.
Product code :
JR 103.
Ingredient
name
|
%
|
CAS
number
|
Isopropyl
alcohol
|
1 - 5
|
67-63-0
|
2-Butoxyethanol
|
1 - 5
|
111-76-2
|
Sulfonic acids, C14-16-alkane hydroxy and C14-16-alkene,
sodium salts
|
0.1 - 1
|
68439-57-6
|
Any concentration shown as a
range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current
knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational
exposure limits, if available, are listed in Section 8.
Section 4. First aid
measures
Description of necessary first aid measuresEye contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention.Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Maintain an open airway. Get medical attention if symptoms occur.Skin
contact: Flush contaminated skin with plenty of water. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.Ingestion: Wash out mouth with water. If
material has been swallowed and the exposed person is conscious, give small
quantities of water to drink. Do not induce vomiting unless directed to do so
by medical personnel. If vomiting occurs, the head should be kept low so that
vomit does not enter the lungs. Never give anything by mouth to an unconscious
person. Get medical attention if symptoms occur.
Most important
symptoms/effects, acute and delayed Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can
cause central nervous system (CNS) depression. May cause drowsiness and
dizziness.
Skin contact : No known significant effects
or critical hazards.
Ingestion: Can
cause central nervous system (CNS) depression. Irritating to mouth, throat and
stomach.
Over-exposure signs/symptomsEye contact :
Adverse symptoms may include the following: pain or irritation watering rednessInhalation: Adverse symptoms may include the following: nausea or vomitingheadache drowsiness/ fatigue/ dizziness/ vertigo unconsciousnessSkin contact: No known significant effects or critical hazards. Ingestion: No
known significant effects or critical hazards.
Indication of
immediate medical attention and special treatment needed, if necessary
Notes to physician : Treat
symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken
involving any personal risk or without suitable training. If it is suspected that fumes are still present,
the rescuer should wear an appropriate mask or
self-contained breathing apparatus.
See
toxicological information (Section 11)
Section 5. Fire-fighting
measures
Extinguishing mediaSuitable extinguishing media: Use dry chemical, CO2, water spray (fog) or foam.Unsuitable extinguishing media: Do not use water jet or water-based fire extinguishers.Specific hazards arising from the chemical: Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.Hazardous thermal decomposition products: Decomposition products may include the following materials: carbon dioxide carbon monoxide
Special
protective actions for fire-fighters: Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Special protective equipment for
fire-fighters: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Personal precautions, protective equipment and emergency
procedures
For non-emergency personnel: Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
For emergency
responders : If specialized clothing is required to deal with the
spillage, take note of any information in Section 8 on suitable and unsuitable
materials. See also the information in "For non- emergency
personnel".
Environmental precautions: Avoid
dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).
Methods and
materials for containment and cleaning up
Spill: Stop
leak if without risk. Move containers from spill area. Use spark-proof tools
and explosion-proof equipment. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage
with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Dispose of via a licensed waste disposal
contractor. Contaminated absorbent material may pose the same hazard as the
spilled product. Note: see Section 1 for emergency contact information and
Section 13 for waste disposal.
Section 7. Handling and
storage
Precautions for safe
handling Protective measures :Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.
Advice on general occupational hygiene: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, including any incompatibilities: Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
Control parameters Occupational exposure
limits
Ingredient
name
|
Exposure
limits
|
Isopropyl alcohol
2-Butoxyethanol
|
ACGIH TLV
(United States, 6/2013).
STEL: 400
ppm 15 minutes.
TWA: 200 ppm 8 hours.
NIOSH REL (United States,
4/2013).
STEL: 1225
mg/m³ 15 minutes.
STEL: 500 ppm 15 minutes.
TWA: 980 mg/m³ 10 hours.
TWA: 400 ppm 10 hours.
OSHA PEL (United States,
2/2013).
TWA: 980
mg/m³ 8 hours.
TWA: 400 ppm 8 hours.
ACGIH TLV
(United States, 6/2013).
TWA: 20 ppm
8 hours.
NIOSH REL (United States,
4/2013). Absorbed through skin.
TWA: 24
mg/m³ 10 hours.
TWA: 5 ppm 10 hours.
OSHA PEL (United States,
2/2013). Absorbed through skin.
TWA: 240
mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
|
Appropriate engineering controls: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Environmental exposure controls: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.
Individual
protection measures Hygiene measures :Wash hands, forearms and face thoroughly after handling chemical
products, before eating,
smoking and using the lavatory and at the end of the working period. Ensure
that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Skin
protection
Skin
protection
Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.
Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
Other skin protection: : Appropriate footwear and any additional skin
protection measures should be selected based
on the task being performed and the risks
involved and should
be approved by a
specialist before handling this product
Respiratory protection: Use a properly
fitted, air-purifying or supplied air respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection
must be based on known
or anticipated exposure
levels, the hazards
of the product and the safe
working limits of the selected respirator.
Section 9. Physical and
chemical properties
Appearance Physical state: Liquid. [Thin.] Color: Clear.
Odor: Alcohol.
Odor threshold: Not available. pH: 7-8.5.
Melting point: Not available.
Boiling point : Not available.
Flash
point: Closed cup: 23 to 37.8°C (73.4 to 100°F) [Pensky-Martens.] Evaporation rate: Not available.
Flammability (solid,
gas) : Not available.
Lower
and upper explosive (flammable) limits: Not available.Vapor Pressure: Not available.Vapor Density: Not available.Relative Density: Not available.Solubility: Not available.
Partition coefficient n- octanol/water: Not available.
Auto-ignition
temperature: Not available.
Decomposition temperature : Not available. Viscosity: Thin.
Section 10. Stability and
reactivity
Reactivity : No
specific test data related to reactivity available for this product or its ingredients.
Chemical stability : The product is stable.
Possibility
of hazardous reactions: Under normal conditions of
storage and use, hazardous reactions will not occur.
Conditions to avoid: Avoid
all possible sources of ignition (spark or flame). Do not pressurize, cut,
weld, braze, solder, drill, grind or expose containers to heat or sources of
ignition.Incompatible materials : Reactive or incompatible with the following
materials: oxidizing materials.
Hazardous
decomposition products: Under
normal conditions of storage and use, hazardous decomposition products should
not be produced.
Information on
toxicological effects Acute toxicity
Product/ingredient
name
|
Result
|
Species
|
Dose
|
Exposure
|
Isopropyl
alcohol
|
LD50 Dermal
|
Rabbit
|
12800 mg/kg
|
-
|
|
LD50 Oral
|
Rat
|
5000 mg/kg
|
-
|
2-Butoxyethanol
|
LC50 Inhalation Vapor
|
Rat
|
450 ppm
|
4 hours
|
|
LD50 Dermal
|
Rabbit
|
220 mg/kg
|
-
|
|
LD50 Oral
|
Rat
|
250 mg/kg
|
-
|
Irritation/Corrosion
Product/ingredient
name
|
Result
|
Species
|
Score
|
Exposure
|
Observation
|
Isopropyl
alcohol
|
Eyes -
Severe irritant
|
Rabbit
|
-
|
100 mg
|
-
|
|
Skin - Mild irritant
|
Rabbit
|
-
|
500 mg
|
-
|
|
Eyes - Moderate irritant
|
Rabbit
|
-
|
24 hours 100 mg
|
-
|
|
Eyes - Moderate irritant
|
Rabbit
|
-
|
10 mg
|
-
|
2-Butoxyethanol
|
Eyes - Moderate irritant
|
Rabbit
|
-
|
24 hours 100 mg
|
-
|
|
Eyes - Severe irritant
|
Rabbit
|
-
|
100 mg
|
-
|
|
Skin - Mild irritant
|
Rabbit
|
-
|
500 mg
|
-
|
Sensitization
There is no data available.
Carcinogenicity Classification
Product/ingredient
name
|
OSHA
|
IARC
|
NTP
|
ACGIH
|
EPA
|
NIOSH
|
Isopropyl
alcohol 2-Butoxyethanol
|
None.
-
|
3
3
|
-
-
|
A4 A3
|
-
-
|
-
-
|
Specific target organ toxicity (single
exposure)
Name
|
Category
|
Route of exposure
|
Target
organs
|
Isopropyl alcohol
|
Category 3
|
Not applicable.
|
Narcotic effects
|
Specific target organ toxicity (repeated exposure)
There is no data available.
Aspiration hazard
There is no data available.
Information
on the likely routes of exposure: Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can
cause central nervous system (CNS) depression. May cause drowsiness and
dizziness.
Skin contact : No known significant effects
or critical hazards.
Ingestion: Can
cause central nervous system (CNS) depression. Irritating to mouth, throat and
stomach.

Symptoms related to the physical, chemical and toxicological characteristics
Eye contact : Adverse
symptoms may include the following: pain or irritation watering
redness
Inhalation: Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness.
Skin contact: No known significant effects or critical hazards. Ingestion: No
known significant effects or critical hazards.
Delayed and
immediate effects and also chronic effects from short and long term exposure Short term exposure
Potential immediate effects: No known significant effects or
critical hazards.
Potential delayed effects :
No known
significant effects or critical hazards.
Long term exposure
Potential immediate effects: No known significant effects or
critical hazards.
Potential delayed effects :
No known
significant effects or critical hazards.
Potential chronic health effects
General :No known significant effects or critical hazards.
Carcinogenicity :No known significant effects or critical hazards.
Mutagenicity :No known significant effects or critical hazards.
Teratogenicity :No known significant effects or critical hazards
Developmental effects : No known significant effects
or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Numerical measures of toxicity Acute toxicity
estimates
Route
|
ATE
value
|
Oral Dermal
Inhalation (vapors)
|
5882.4 mg/kg
7333.3 mg/kg
366.7 mg/L
|
Section 12. Ecological
information
Toxicity
Product/ingredient
name
|
Result
|
Species
|
Exposure
|
Isopropyl
alcohol 2-Butoxyethanol
Sulfonic acids,
C14-16-alkane hydroxy and C14-16-alkene, sodium salts
|
Acute LC50 1400000 to 1950000 µg/l Marine water
Acute LC50 1400000 µg/l
Acute EC50 >1000 mg/L
Fresh water Acute LC50 1000 mg/L Marine water
Acute LC50 1250000 µg/l
Marine water Acute EC50 4.53 mg/L Fresh water
|
Crustaceans - Crangon crangon Fish - Gambusia affinis
Daphnia - Daphnia magna
Crustaceans
- Chaetogammarus marinus - Young
Fish - Menidia beryllina
Crustaceans - Ceriodaphnia dubia - Neonate
|
48 hours
96 hours
48 hours
48 hours
96 hours
48 hours
|
Persistence and degradability
There is no data available.
Bioaccumulative
potential
Product/ingredient
name
|
LogPow
|
BCF
|
Potential
|
Isopropyl alcohol
2-Butoxyethanol
|
0.05
0.81
|
-
-
|
low low
|
Mobility in soil
Soil/water partition coefficient (KOC): There is no data available.
Other adverse
effects : No known significant effects
or critical hazards.
Section 13. Disposal
considerations
Disposal methods: The generation of waste should be
avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should comply
with the requirements of environmental protection and waste disposal
legislation and any regional local authority requirements. Dispose of surplus
and non-recyclable products via a licensed waste disposal contractor. Waste
should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Waste packaging should be recycled.
Incineration or landfill should only be considered when recycling is not
feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling
empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some
product residues. Vapor from product
residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff
and contact with soil, waterways, drains and
sewers.
Section 14. Transport
information
|
DOT
Classification
|
IMDG
|
IATA
|
UN
number
|
NOT REGULATED
|
NOT REGULATED
|
NOT REGULATED
|
UN proper shipping name
|
|
|
|
Transport hazard class(es)
|
|
|
|
Packing
group
|
|
|
|
Environmental hazards
|
No.
|
No.
|
No.
|
Additional information
|
-
|
|
|
AERG NOT APPLICABLE
Special precautions for user: Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according to Annex II of MARPOL 73/78 and
the IBC Code: Not available.
Section 15. Regulatory
information
U.S. Federal
regulations :TSCA 8(a) CDR Exempt/Partial
exemption:
Not determined
United States
inventory (TSCA 8b): All components are listed or exempted.
Clean Air Act Section
112
(b) Hazardous Air Pollutants (HAPs): Not listed
Clean Air Act Section 602 Class I
Substances: Not listed
Clean Air Act Section 602 Class II
Substances: Not listed
DEA List I Chemicals (Precursor Chemicals): Not listed
DEA List II Chemicals (Essential Chemicals): Not listed
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ :
Not applicable.
SARA 311/312
Classification : Fire hazard / Immediate (acute) health hazard
Composition/information on ingredients
Name
|
%
|
Fire hazard
|
Sudden release of pressure
|
Reactive
|
Immediate (acute) health hazard
|
Delayed (chronic) health hazard
|
Isopropyl
alcohol
|
1 - 5
|
No.
|
No.
|
No.
|
Yes.
|
No.
|
2-Butoxyethanol
|
1 - 5
|
No.
|
No.
|
No.
|
Yes.
|
No.
|
Sulfonic acids, C14-16-
alkane hydroxy and
|
0.1 - 1
|
No.
|
No.
|
No.
|
Yes.
|
No.
|
C14-16-alkene, sodium salts
|
|
|
|
|
|
|
SARA 313
|
Product
name
|
CAS
number
|
%
|
Form R - Reporting requirements
|
Isopropyl
alcohol 2-Butoxyethanol
|
67-63-0
111-76-2
|
1 - 5
1 - 5
|
Supplier
notification
|
Isopropyl
alcohol 2-Butoxyethanol
|
67-63-0
111-76-2
|
1 - 5
1 - 5
|
SARA 313 notifications must not
be detached from the SDS and any copying and redistribution of the SDS shall
include copying and redistribution of the notice attached to copies of the SDS
subsequently redistributed.
State
regulations Massachusetts :The following components are
listed: Isopropyl alcohol; 2-Butoxyethanol
New York : None of the components are listed.
New Jersey : The following components are
listed: Isopropyl alcohol; 2-Butoxyethanol
Pennsylvania : The following components are
listed: Isopropyl alcohol; 2-Butoxyethanol
California Prop. 65
No
products were found.
Section 16. Other
information
History
Date of issue mm/dd/yyyy: 05/15/2014
Version: 1
Revised Section(s) : Not applicable.
Prepared by : KMK Regulatory Services Inc.
Key to abbreviations :
ATE
= Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System
of Classification and Labelling of Chemicals IATA = International Air Transport
Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International
Convention for the Prevention of Pollution From Ships, 1973 as modified by the
Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Notice to
reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
subsidiaries, assumes any liability whatsoever for the accuracy
or completeness of the information contained herein.
Final determination of suitability of any material
is the sole responsibility of the user. All materials may present unknown
hazards and should
be used with caution.
Although certain hazards
are described herein,
we cannot guarantee that these are the only hazards that exist.
|