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Conforms to HazCom 2012/United States
SAFETY DATA SHEET
JR-103 Clear- Glass Cleaner


Section 1. Identification


GHS product identifier: JR-103 Clear-Glass Cleaner

Other means of identification: JR-103.

Product type: Liquid.

Identified Uses: Glass cleaner.

Supplier's details :

Renu Chem Inc.

572 Malloy Ct

Corona Ca 92880

Tel: 951 736 8072

Toll Free: 800 721 5572

Fax: 951 344 0466

Email: [email protected] Web site: www.Renuchem.com


Emergency telephone number (with hours of operation): CHEMTREC, U.S. : 1-800-424-9300 International: +1-703-527-3887 (24/7)


Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).


Classification of the substance or mixture: SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -

Category 3


GHS label elements

Signal word : Warning

Hazard statements : Flammable liquid and vapor.

Causes serious eye irritation.

May cause drowsiness and dizziness.

Precautionary statements

Prevention : Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion- proof electrical, ventilating, lighting and all material-handling equipment. Use only non- sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Avoid breathing vapor.

Wash hands thoroughly after handling.


Response : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage : Store locked up. Store in a well-ventilated place. Keep cool.

Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.


Hazards not otherwise classified: None known.


Section 3. Composition/information on ingredients

Substance/mixture : Mixture


Other means of identification: Not available.


CAS number/other identifiers

CAS number : Not applicable.

Product code : JR 103.

Ingredient name

%

CAS number

Isopropyl alcohol

1 - 5

67-63-0

2-Butoxyethanol

1 - 5

111-76-2

Sulfonic acids, C14-16-alkane hydroxy and C14-16-alkene,

sodium salts

0.1 - 1

68439-57-6

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.


Section 4. First aid measures

Description of necessary first aid measures

Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention.

Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Maintain an open airway. Get medical attention if symptoms occur.

Skin contact: Flush contaminated skin with plenty of water. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Ingestion: Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. Get medical attention if symptoms occur.

Most important symptoms/effects, acute and delayed Potential acute health effects


Eye contact : Causes serious eye irritation.

Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness.

Skin contact : No known significant effects or critical hazards.


Ingestion: Can cause central nervous system (CNS) depression. Irritating to mouth, throat and stomach.


Over-exposure signs/symptoms

Eye contact : Adverse symptoms may include the following: pain or irritation watering redness

Inhalation: Adverse symptoms may include the following: nausea or vomiting

headache drowsiness/ fatigue/ dizziness/ vertigo unconsciousness

Skin contact: No known significant effects or critical hazards.

Ingestion: No known significant effects or critical hazards.


Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments : No specific treatment.

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus.

See toxicological information (Section 11)


Section 5. Fire-fighting measures


Extinguishing media

Suitable extinguishing media: Use dry chemical, CO2, water spray (fog) or foam.

Unsuitable extinguishing media: Do not use water jet or water-based fire extinguishers.

Specific hazards arising from the chemical: Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.

Hazardous thermal decomposition products: Decomposition products may include the following materials: carbon dioxide carbon monoxide


Special protective actions for fire-fighters: Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.


Personal precautions, protective equipment and emergency procedures


For non-emergency personnel: Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel".


Environmental precautions: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).


Methods and materials for containment and cleaning up


Spill: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.


Section 7. Handling and storage


Precautions for safe handling

Protective measures :Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.


Advice on general occupational hygiene: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures.


Conditions for safe storage, including any incompatibilities: Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Control parameters Occupational exposure limits

Ingredient name

Exposure limits

Isopropyl alcohol

2-Butoxyethanol

ACGIH TLV (United States, 6/2013).

STEL: 400 ppm 15 minutes.

TWA: 200 ppm 8 hours.

NIOSH REL (United States, 4/2013).

STEL: 1225 mg/m³ 15 minutes.

STEL: 500 ppm 15 minutes.

TWA: 980 mg/m³ 10 hours.

TWA: 400 ppm 10 hours.

OSHA PEL (United States, 2/2013).

TWA: 980 mg/m³ 8 hours.

TWA: 400 ppm 8 hours.

ACGIH TLV (United States, 6/2013).

TWA: 20 ppm 8 hours.

NIOSH REL (United States, 4/2013). Absorbed through skin.

TWA: 24 mg/m³ 10 hours.

TWA: 5 ppm 10 hours.

OSHA PEL (United States, 2/2013). Absorbed through skin.

TWA: 240 mg/m³ 8 hours.

TWA: 50 ppm 8 hours.


Appropriate engineering controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Environmental exposure controls: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.


Individual protection measures

Hygiene measures :Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Ensure that eyewash stations and safety showers are close to the workstation location.


Eye/face protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.


Skin protection

Skin protection

Hand protection
: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.

Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

Other skin protection: : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product

Respiratory protection: Use a properly fitted, air-purifying or supplied air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.


Section 9. Physical and chemical properties


Appearance

Physical state: Liquid. [Thin.]

Color: Clear.


Odor: Alcohol.

Odor threshold: Not available.

pH: 7-8.5.

Melting point: Not available.

Boiling point : Not available.

Flash point: Closed cup: 23 to 37.8°C (73.4 to 100°F) [Pensky-Martens.]

Evaporation rate: Not available.

Flammability (solid, gas) : Not available.

Lower and upper explosive (flammable) limits: Not available.

Vapor Pressure: Not available.

Vapor Density: Not available.

Relative Density: Not available.

Solubility: Not available.

Partition coefficient n- octanol/water: Not available.

Auto-ignition temperature: Not available.

Decomposition temperature : Not available.
Viscosity: Thin.


Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid: Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials.

Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should not be produced.


Information on toxicological effects Acute toxicity

Product/ingredient name

Result

Species

Dose

Exposure

Isopropyl alcohol

LD50 Dermal

Rabbit

12800 mg/kg

-

LD50 Oral

Rat

5000 mg/kg

-

2-Butoxyethanol

LC50 Inhalation Vapor

Rat

450 ppm

4 hours

LD50 Dermal

Rabbit

220 mg/kg

-

LD50 Oral

Rat

250 mg/kg

-

Irritation/Corrosion

Product/ingredient name

Result

Species

Score

Exposure

Observation

Isopropyl alcohol

Eyes - Severe irritant

Rabbit

-

100 mg

-

Skin - Mild irritant

Rabbit

-

500 mg

-

Eyes - Moderate irritant

Rabbit

-

24 hours 100 mg

-

Eyes - Moderate irritant

Rabbit

-

10 mg

-

2-Butoxyethanol

Eyes - Moderate irritant

Rabbit

-

24 hours 100 mg

-

Eyes - Severe irritant

Rabbit

-

100 mg

-

Skin - Mild irritant

Rabbit

-

500 mg

-

Sensitization

There is no data available.

Carcinogenicity Classification

Product/ingredient name

OSHA

IARC

NTP

ACGIH

EPA

NIOSH

Isopropyl alcohol 2-Butoxyethanol

None.

-

3

3

-

-

A4 A3

-

-

-

-

Specific target organ toxicity (single exposure)

Name

Category

Route of exposure

Target organs

Isopropyl alcohol

Category 3

Not applicable.

Narcotic effects

Specific target organ toxicity (repeated exposure)

There is no data available.

Aspiration hazard

There is no data available.


Information on the likely routes of exposure: Dermal contact. Eye contact. Inhalation. Ingestion.


Potential acute health effects

Eye contact : Causes serious eye irritation.

Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness.

Skin contact : No known significant effects or critical hazards.


Ingestion: Can cause central nervous system (CNS) depression. Irritating to mouth, throat and stomach.


Symptoms related to the physical, chemical and toxicological characteristics Eye contact : Adverse symptoms may include the following: pain or irritation watering redness

Inhalation: Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness.

Skin contact: No known significant effects or critical hazards.

Ingestion: No known significant effects or critical hazards.

Delayed and immediate effects and also chronic effects from short and long term exposure

Short term exposure


Potential immediate effects: No known significant effects or critical hazards.


Potential delayed effects : No known significant effects or critical hazards.

Long term exposure


Potential immediate effects: No known significant effects or critical hazards.


Potential delayed effects : No known significant effects or critical hazards.

Potential chronic health effects


General :No known significant effects or critical hazards.

Carcinogenicity :No known significant effects or critical hazards.

Mutagenicity :No known significant effects or critical hazards.

Teratogenicity :No known significant effects or critical hazards

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity Acute toxicity estimates

Route

ATE value

Oral Dermal

Inhalation (vapors)

5882.4 mg/kg

7333.3 mg/kg

366.7 mg/L


Section 12. Ecological information

Toxicity

Product/ingredient name

Result

Species

Exposure

Isopropyl alcohol 2-Butoxyethanol

Sulfonic acids, C14-16-alkane hydroxy and C14-16-alkene, sodium salts

Acute LC50 1400000 to 1950000 µg/l Marine water Acute LC50 1400000 µg/l

Acute EC50 >1000 mg/L Fresh water Acute LC50 1000 mg/L Marine water

Acute LC50 1250000 µg/l Marine water Acute EC50 4.53 mg/L Fresh water

Crustaceans - Crangon crangon Fish - Gambusia affinis Daphnia - Daphnia magna

Crustaceans - Chaetogammarus marinus - Young

Fish - Menidia beryllina Crustaceans - Ceriodaphnia dubia - Neonate

48 hours

96 hours

48 hours

48 hours

96 hours

48 hours

Persistence and degradability

There is no data available.

Bioaccumulative potential

Product/ingredient name

LogPow

BCF

Potential

Isopropyl alcohol 2-Butoxyethanol

0.05

0.81

-

-

low low


Mobility in soil

Soil/water partition coefficient (KOC): There is no data available.


Other adverse effects : No known significant effects or critical hazards.


Section 13. Disposal considerations


Disposal methods: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.


Section 14. Transport information

DOT Classification

IMDG

IATA

UN number

NOT REGULATED

NOT REGULATED

NOT REGULATED

UN proper shipping name

Transport hazard class(es)

Packing group

Environmental hazards

No.

No.

No.

Additional information

-

AERG NOT APPLICABLE


Special precautions for user: Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not available.



Section 15. Regulatory information


U.S. Federal regulations :TSCA 8(a) CDR Exempt/Partial exemption: Not determined

United States inventory (TSCA 8b): All components are listed or exempted.



Clean Air Act Section 112

(b) Hazardous Air Pollutants (HAPs): Not listed

Clean Air Act Section 602 Class I Substances: Not listed

Clean Air Act Section 602 Class II Substances: Not listed

DEA List I Chemicals (Precursor Chemicals): Not listed

DEA List II Chemicals (Essential Chemicals): Not listed

SARA 302/304


Composition/information on ingredients

No products were found.


SARA
304 RQ : Not applicable.

SARA 311/312

Classification : Fire hazard / Immediate (acute) health hazard

Composition/information on ingredients

Name

%

Fire hazard

Sudden release of pressure

Reactive

Immediate (acute) health hazard

Delayed (chronic) health hazard

Isopropyl alcohol

1 - 5

No.

No.

No.

Yes.

No.

2-Butoxyethanol

1 - 5

No.

No.

No.

Yes.

No.

Sulfonic acids, C14-16-

alkane hydroxy and

0.1 - 1

No.

No.

No.

Yes.

No.

C14-16-alkene, sodium salts

SARA 313

Product name

CAS number

%

Form R - Reporting requirements

Isopropyl alcohol 2-Butoxyethanol

67-63-0

111-76-2

1 - 5

1 - 5

Supplier notification

Isopropyl alcohol 2-Butoxyethanol

67-63-0

111-76-2

1 - 5

1 - 5

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.


State regulations

Massachusetts :The following components are listed: Isopropyl alcohol; 2-Butoxyethanol


New York : None of the components are listed.

New Jersey : The following components are listed: Isopropyl alcohol; 2-Butoxyethanol

Pennsylvania : The following components are listed: Isopropyl alcohol; 2-Butoxyethanol

California Prop. 65

No products were found.


Section 16. Other information


History

Date of issue mm/dd/yyyy: 05/15/2014


Version: 1

Revised Section(s) : Not applicable.

Prepared by : KMK Regulatory Services Inc.

Key to abbreviations : ATE = Acute Toxicity Estimate

BCF = Bioconcentration Factor

GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association

IBC = Intermediate Bulk Container

IMDG = International Maritime Dangerous Goods

LogPow = logarithm of the octanol/water partition coefficient

MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)

UN = United Nations

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.