Conforms to HazCom 2012/United States SAFETY DATA SHEET JR-101 Yellow -
Degreaser
Section
1. Identification
GHS product identifier: JR-101 Yellow- DegreaserOther
means of identification: JR-101
Product type: Liquid.Identified uses: Cleaner
degreaser.
Emergency telephone
number (with hours of operation): CHEMTREC,
U.S. : 1-800-424-9300 International: +1-703-527-3887 (24/7)
Section
2. Hazards identification
OSHA/HCS status : This
material is considered hazardous by the OSHA Hazard Communication Standard (29
CFR 1910.1200).
Classification of the substance or mixture: SKIN
CORROSION/IRRITATION - Category 1
SERIOUS
EYE DAMAGE/ EYE IRRITATION - Category 1 AQUATIC HAZARD (LONG-TERM) - Category 3
Signal word: Warning
Hazard statements: Causes
severe skin burns and eye damage.
Harmful to aquatic
life with long lasting effects.
Precautionary statements
Prevention:
Wear protective
gloves. Wear eye or face protection. Wear protective clothing. Avoid release
to the environment. Wash hands thoroughly after handling.
Response:
IF INHALED: Remove
victim to fresh air and keep at rest in a position comfortable for breathing.
Immediately call a POISON CENTER or physician. IF SWALLOWED: Immediately call a
POISON CENTER or physician. Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or
hair): Take off immediately all contaminated clothing. Rinse skin with water or
shower. Wash contaminated clothing before reuse. Immediately call a POISON
CENTER or physician. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a
POISON CENTER or physician.
Storage: Store
locked up.
Disposal: Dispose
of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label elements: Do not taste or swallow. Wash thoroughly after handling.
Hazards
not otherwise classified: Causes severe digestive tract burns.
Section
3. Composition/information on ingredients Substance/mixture : Mixture Other means of identification: Not available.
CAS number/other identifiers
CAS
number : Not applicable.
Product code : JR-101
Ingredient name
|
%
|
CAS number
|
Sodium hydroxide
|
1 - 10
|
1310-73-2
|
2-Butoxyethanol
|
1 - 5
|
111-76-2
|
Nonylphenol, ethoxylated
|
1 - 5
|
9016-45-9
|
Sodium xylenesulphonate
|
1 - 5
|
1300-72-7
|
Dodecylbenzenesulphonic acid
|
1 - 5
|
27176-87-0
|
Any
concentration shown as a range is to protect confidentiality or is due to batch
variation.
There are no additional ingredients present which, within the current knowledge
of the supplier and in the concentrations applicable, are
classified as hazardous to health
or the environment and hence
require reporting in this section.
Occupational exposure limits, if available, are listed
in Section 8.
Section
4. First aid measures
Description of necessary first
aid measures
Eye contact: Get
medical attention immediately. Call a poison center or physician. Immediately
flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at
least 20 minutes. Chemical burns must be treated promptly by a physician.
Inhalation :Get
medical attention immediately. Call a poison center or physician. Remove victim
to fresh air and keep at rest in a position comfortable for breathing. If it is
suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Maintain an open airway. Loosen tight
clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition
products in a fire, symptoms may be delayed. The exposed person may need to be
kept under medical surveillance for 48 hours.
Skin contact: Get
medical attention immediately. Call a poison center or physician. Wash with plenty
of soap and water. Wash contaminated clothing thoroughly with water before
removing it, or wear gloves. Continue to rinse for at least 20 minutes.
Chemical burns must be treated promptly by a physician. In the event of any
complaints or symptoms, avoid further exposure.
Ingestion :Get
medical attention immediately. Call a poison center or physician. Wash out
mouth with water. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless
directed to do so by medical personnel. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Chemical burns must be
treated promptly by a physician. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately.
Most important symptoms/effects, acute and delayed Potential acute health effects
Eye contact : Causes
serious eye damage.
Inhalation :
May give off gas,
vapor or dust that is very irritating or corrosive to the respiratory system.
Skin contact:
Causes severe burns.
Ingestion: Severely
corrosive to the digestive tract. Causes severe burns. May cause burns to
mouth, throat and stomach.
Over-exposure
signs/symptomsEye contact :
Adverse symptoms may include the following: pain, watering, rednessInhalation: No known significant effects or critical hazards. Skin Contact: Adverse symptoms may include the following: pain or irritationredness, blistering may occur. Ingestion: Adverse symptoms may include the following: stomach pains
Indication of immediate medical attention and special treatment
needed, if necessary
Notes to physician :
Treat
symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No
action shall be taken involving any personal risk or without suitable training.
If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly
with water before removing it, or wear gloves.
See toxicological information (Section 11)
Extinguishing mediaSuitable
extinguishing media: Use an extinguishing agent suitable for the surrounding fire.Unsuitable extinguishing media: None known.Specific hazards arising from the chemical: This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.Hazardous
thermal decomposition products : Decomposition products may include the following materials: carbon dioxide, carbon monoxide, Sulfur oxides, metal oxide/oxides.
Special protective actions for fire-fighters: No special measures are required.Special
protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section
6. Accidental release measures
Personal precautions,
protective equipment and emergency proceduresFor non-emergency personnel: No
action shall be taken involving any personal risk or without suitable training. Evacuate
surrounding areas. Keep unnecessary and unprotected personnel from entering. Do
not touch or walk through spilled material. Do not breathe vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.For emergency responders : If specialized clothing is required to deal with the
spillage, take note of any information in Section 8 on suitable and unsuitable
materials. See also the information in "For non- emergency
personnel".
Environmental precautions: Avoid
dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air). Water polluting
material. May be harmful to the environment if released in large quantities.
Methods and materials for containment and cleaning up
Spill: Stop
leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry
into sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage
with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Dispose of via a licensed waste disposal
contractor. Contaminated absorbent material may pose the same hazard as the
spilled product. Note: see Section 1 for
emergency contact information and
Section 13 for waste disposal.
Precautions for safe handling Protective
measures : Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid release to the environment. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Keep away from acids. Empty containers retain product residue and can be hazardous. Do not reuse container.Advice on general occupational hygiene: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures. Remove contaminated clothing and protective equipment before entering eating areas.
Conditions
for safe storage, including
any incompatibilities: Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Separate from acids. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
Section
8. Exposure controls/personal protection
Control parameters Occupational exposure limits
Ingredient name
|
Exposure limits
|
Sodium
hydroxide
2-Butoxyethanol
|
ACGIH TLV (United States, 6/2013).
C: 2 mg/m³
NIOSH
REL (United States, 4/2013).
CEIL: 2 mg/m³
OSHA
PEL (United States, 2/2013).
TWA: 2 mg/m³ 8
hours.
ACGIH TLV (United States, 6/2013).
TWA: 20 ppm 8 hours.
NIOSH
REL (United States, 4/2013). Absorbed through skin.
TWA: 24 mg/m³ 10 hours.
TWA: 5 ppm 10 hours.
OSHA
PEL (United States, 2/2013). Absorbed through skin.
TWA: 240 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
|
Appropriate
engineering controls: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Environmental
exposure controls: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Individual protection measures Hygiene measures :Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be
used to remove potentially contaminated clothing. Wash contaminated clothing
before reusing. Ensure that eyewash stations and safety showers are close to
the workstation location.
Eye/face protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/ or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Skin protection Hand Protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Recommended: Nitrile gloves. Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection :
Appropriate
footwear and any additional skin protection measures should be selected based on the task being performed and the risks
involved and should
be approved by a
specialist before handling this product. Respiratory protection:Use a properly fitted, air-purifying
or supplied air respirator complying with an approved standard if a risk
assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure
levels, the hazards
of the product and the safe
working limits of the selected respirator.
Section
9. Physical and chemical properties
Appearance Physical state: Liquid (Medium Bodied). Color: Yellow.
Odor: Spice.
Odor
threshold: Not available. pH: 12.5-14
Melting
point: Not available.
Boiling point :
>93.33°C (>200°F) Flash point: Closed cup: 93.333°C (200°F) [Pensky-Martens.] Evaporation rate: Not available. Flammability (solid,
gas) : Not available. Lower and upper explosive (flammable) limits: Not available. Vapor pressure: >0.13 kPa (>1 mm Hg) [room temperature]
Vapor density: >1 [Air = 1] Relative density: 0.986 to 1.15 Solubility: Completely miscible in water.
Partition
coefficient n- octanol/water: Not available.
Auto-ignition temperature: Not available. Decomposition temperature : Not
available. Viscosity: Medium Bodied. Reactivity:
No specific test
data related to reactivity available for this product or its ingredients.
Chemical stability:
The product is stable. Possibility of hazardous reactions: Under normal conditions of storage
and use, hazardous reactions will not occur.
Conditions to avoid : No
specific data.
Incompatible materials :
Reactive or incompatible with the following materials:
oxidizing materials and alkalis.
Hazardous decomposition
products: Under
normal conditions of storage and use, hazardous decomposition products should
not be produced.
Section
11. Toxicological information
Information on toxicological effects Acute toxicity
Product/ingredient name
|
Result
|
Species
|
Dose
|
Exposure
|
2-Butoxyethanol
|
LC50 Inhalation Vapor
|
Rat
|
450 ppm
|
4 hours
|
|
LD50 Dermal
|
Rabbit
|
220 mg/kg
|
-
|
|
LD50 Oral
|
Rat
|
250 mg/kg
|
-
|
Sodium xylenesulphonate
|
LD50 Oral
|
Rat
|
7200 mg/kg
|
-
|
Dodecylbenzenesulphonic acid
|
LD50 Oral
|
Rat
|
650 mg/kg
|
-
|
Irritation/Corrosion
Product/ingredient name
|
Result
|
Species
|
Score
|
Exposure
|
Observation
|
Sodium hydroxide
|
Eyes - Severe irritant
|
Monkey
|
-
|
24 hours 1%
|
-
|
|
Eyes - Mild irritant
|
Rabbit
|
-
|
400 µg
|
-
|
|
Eyes - Severe irritant
|
Rabbit
|
-
|
24 hours 50 µg
|
-
|
|
Eyes - Severe irritant
|
Rabbit
|
-
|
1%
|
-
|
|
Eyes - Severe irritant
|
Rabbit
|
-
|
0.5 minutes 1 mg
|
-
|
|
Skin - Mild irritant
|
Human
|
-
|
24 hours 2 %
|
-
|
|
Skin - Severe irritant
|
Rabbit
|
-
|
24 hours 500 mg
|
-
|
2-Butoxyethanol
|
Eyes - Moderate irritant
|
Rabbit
|
-
|
24 hours 100 mg
|
-
|
|
Eyes - Severe irritant
|
Rabbit
|
-
|
100 mg
|
-
|
|
Skin - Mild irritant
|
Rabbit
|
-
|
500 mg
|
-
|
Nonylphenol, ethoxylated
|
Eyes - Severe irritant
|
Guinea pig
|
-
|
20 mg
|
-
|
|
Eyes - Severe irritant
|
Mouse
|
-
|
20 mg
|
-
|
|
Eyes - Severe irritant
|
Rabbit
|
-
|
20 mg
|
-
|
|
Skin - Mild irritant
|
Human
|
-
|
72 hours 15 mg
|
-
|
|
|
|
|
Intermittent
|
|
|
Skin - Mild irritant
|
Rabbit
|
-
|
500 mg
|
-
|
Dodecylbenzenesulphonic acid
|
Skin - Severe irritant
|
Rabbit
|
-
|
0.5 mL
|
-
|
Sensitization
There
is no data available.
Carcinogenicity Classification
Product/ingredient name
|
OSHA
|
IARC
|
NTP
|
ACGIH
|
EPA
|
NIOSH
|
2-Butoxyethanol
|
-
|
3
|
-
|
A3
|
-
|
-
|
Specific
target organ toxicity (single exposure)
There
is no data available.
Specific target organ
toxicity (repeated exposure)
There
is no data available.
Aspiration hazard
There
is no data available.
Information on the likely routes of exposure: Dermal contact. Eye contact. Inhalation. Ingestion.
Potential
acute health effects
Eye contact :
Causes serious eye damage.
Inhalation :
May give off gas,
vapor or dust that is very irritating or corrosive to the respiratory system.
Skin contact :
Causes severe burns.
Ingestion: Severely
corrosive to the digestive tract. Causes severe burns. May cause burns to
mouth, throat and stomach.
Symptoms related
to the physical, chemical and toxicological characteristics
Eye contact :
Adverse symptoms may include the following: pain watering redness.
Inhalation: No known significant effects or critical hazards.Skin contact: Adverse symptoms may include the following: pain or irritationredness, blistering may occur.
Ingestion: Adverse symptoms may include the following: stomach pains
Delayed and immediate effects and also chronic effects from short
and long term exposure Short term exposure
Potential immediate effects: No
known significant effects or critical hazards.
Potential delayed
effects : No
known significant effects or critical hazards.
Long term exposure
Potential
immediate effects: No known significant effects or
critical hazards.
Potential delayed
effects: No
known significant effects or critical hazards.
Potential chronic health
effects
General :No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known
significant effects or critical hazards.
Fertility effects : No known
significant effects or critical hazards.
Developmental effects : No known
significant effects or critical hazards.Fertility effects : No known
significant effects or critical hazards.
Numerical measures of toxicity Acute
toxicity estimates
JR-101
Yellow-Degreaser
|
Section 11. Toxicological information
|
|
Route
|
ATE value
|
Oral
Dermal
Inhalation (vapors)
|
4548.6 mg/kg
4400 mg/kg
220 mg/L
|
Toxicity
Product/ingredient name
|
Result
|
Species
|
Exposure
|
Sodium
hydroxide
2-Butoxyethanol
Nonylphenol,
ethoxylated
|
Acute EC50
40.38 mg/L Fresh water
Acute LC50 125 ppm Fresh water Acute EC50 >1000
mg/L Fresh water Acute LC50 1000 mg/L Marine water
Acute LC50 1250000
µg/l Marine water Acute EC50 12 mg/L Fresh water
Acute LC50 1.23 mg/L Marine water Acute LC50 0.148 mg/L Fresh water Acute
LC50 4700 µg/l Fresh water Chronic NOEC 8 mg/L Fresh water Chronic NOEC 35
µg/l Fresh water
|
Crustaceans -
Ceriodaphnia dubia - Neonate
Fish - Gambusia affinis - Adult Daphnia - Daphnia
magna
Crustaceans -
Chaetogammarus marinus - Young
Fish - Menidia beryllina
Algae - Pseudokirchneriella subcapitata Crustaceans -
Americamysis bahia Daphnia - Daphnia magna - Neonate Fish - Oncorhynchus
mykiss
Algae - Pseudokirchneriella subcapitata Fish -
Oryzias latipes - Fry
|
48 hours
96 hours
48 hours
48 hours
96 hours
96 hours
48 hours
48 hours
96 hours
96 hours
100 days
|
Persistence and
degradability
There
is no data available.
Bioaccumulative potential
Product/ingredient name
|
LogPow
|
BCF
|
Potential
|
2-Butoxyethanol
Sodium
xylenesulphonate
|
0.81
-3.12
|
-
-
|
low low
|
Mobility
in soil
Soil/water
partition coefficient
(KOC): There is no data available.
Other adverse effects :
No known significant effects or critical hazards
Section
13. Disposal considerations
Disposal methods: The generation of waste should be
avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should comply
with the requirements of environmental protection and waste disposal
legislation and any regional local authority requirements. Dispose of surplus
and non-recyclable products via a licensed waste disposal contractor. Waste
should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Waste packaging should be recycled.
Incineration or landfill should only be considered when recycling is not
feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling
empty containers that have not been cleaned or rinsed out. Empty containers or
liners may retain some product residues. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.Special precautions for user: Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.Transport
in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not available.
Section
15. Regulatory information
U.S. Federal regulations: TSCA
8(a) PAIR: Nonylphenol, ethoxylated
TSCA
8(a) CDR Exempt/Partial exemption: Not determined
United
States inventory (TSCA 8b): All components are listed or
exempted.
Clean
Water Act (CWA) 311: Sodium hydroxide;
Dodecylbenzenesulphonic acid
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs): Not listed
Clean
Air Act Section 602 Class I Substances: Not listed
Clean
Air Act Section 602 Class II Substances: Not listed
DEA List
I Chemicals (Precursor Chemicals): Not listed
DEA List
II Chemicals (Essential Chemicals): Not listed
SARA 302/304
Composition/information
on ingredients
No
products were found.
SARA 304 RQ :
Not applicable.
SARA 311/312
Classification : Reactive
Immediate (acute)
health hazard
Composition/information
on ingredients
Name
|
%
|
Fire
hazard
|
Sudden
release of pressure
|
Reactive
|
Immediate (acute) health hazard
|
Delayed
(chronic) health hazard
|
Sodium hydroxide
|
1 - 10
|
No.
|
No.
|
Yes.
|
Yes.
|
No.
|
2-Butoxyethanol
|
1 - 5
|
No.
|
No.
|
No.
|
Yes.
|
No.
|
Nonylphenol, ethoxylated
|
1 - 5
|
No.
|
No.
|
No.
|
Yes.
|
No.
|
Sodium xylenesulphonate
|
1 - 5
|
No.
|
No.
|
No.
|
Yes.
|
No.
|
Dodecylbenzenesulphonic acid
|
1 - 5
|
No.
|
No.
|
No.
|
Yes.
|
No.
|
SARA
313
|
Product name
|
CAS number
|
%
|
Form R
- Reporting requirements
|
2-Butoxyethanol
|
111-76-2
|
1 - 5
|
Supplier notification
|
2-Butoxyethanol
|
111-76-2
|
1 - 5
|
SARA
313 notifications must not be detached from the SDS and any copying and
redistribution of the SDS shall include copying and redistribution of the
notice attached to copies of the SDS subsequently redistributed.
State regulations
Massachusetts: The following components are listed: Sodium hydroxide; 2-Butoxyethanol; Dodecylbenzenesulphonic acid.
New York: The
following components are listed: Sodium hydroxide; Dodecylbenzenesulphonic acid
New Jersey:
The following
components are listed: Sodium hydroxide; 2-Butoxyethanol;
Dodecylbenzenesulphonic
acid
Pennsylvania : The following components are listed:
Sodium hydroxide; 2-Butoxyethanol; Dodecylbenzenesulphonic
acid
California Prop. 65No
products were found.
Section
16. Other information
History
Date of issue mm/dd/yyyy: 03/15/2014
Version : 1
Revised Section(s) : Not
applicable.
Prepared by :
KMK Regulatory Services Inc.
Key to abbreviations : ATE
= Acute Toxicity Estimate
BCF =
Bioconcentration Factor
GHS
= Globally Harmonized System of Classification and Labelling of Chemicals IATA
= International Air Transport Association
IBC = Intermediate
Bulk Container
IMDG = International
Maritime Dangerous Goods
LogPow = logarithm of
the octanol/water partition coefficient
MARPOL
73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Notice
to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
subsidiaries, assumes any liability whatsoever for the accuracy
or completeness of the information contained herein.
Final determination of suitability of any material
is the sole responsibility of the user. All materials may present unknown
hazards and should
be used with caution.
Although certain hazards
are described herein,
we cannot guarantee that these are the only hazards that exist.
|