Com 2012/United States SAFETY
DATA SHEET JR-102 Green - All Purpose Cleaner
Section 1. Identification GHS product
identifier: JR-102 Green- All Purpose Cleaner Other means of identification: JR-102. Product type: Liquid. Identified uses: Shampoo.Supplier's details :
Renu Chem Inc.
572 Malloy Ct
Corona Ca
92880
Tel: 951 736
8072
Toll Free: 800
721 5572
Fax: 951 344
0466
Emergency telephone number (with hours of
operation): CHEMTREC, U.S. : 1-800-424-9300 International: +1-703-527-3887 (24/7)
Section 2. Hazards
identification
OSHA/HCS
status : This material is considered
hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Classification of the substance or mixture: SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE
DAMAGE/ EYE IRRITATION - Category 2
GHS label elements
Signal word : Warning
Hazard statements : Causes serious eye irritation. Causes skin
irritation.
Precautionary statements
Prevention : Wear protective gloves. Wear eye or face protection. Wash hands thoroughly after handling.
Response : IF ON SKIN: Wash with plenty
of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin
irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with
water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage : Not applicable.
Disposal : Not applicable.
Hazards
not otherwise classified: None known.
Section 3. Composition/information
on ingredients
Substance/mixture : Mixture
Other
means of identification: Not available.
CAS number/other identifiers
CAS number : Not applicable.
Product code : JR-102.
Ingredient
name
|
%
|
CAS
number
|
Disodium metasilicate
|
1 - 15
|
6834-92-0
|
Alcohols, C9-11,
ethoxylated
|
1 - 15
|
68439-46-3
|
Alcohols, C10-16,
ethoxylated, sulfates, sodium salts
|
1 - 15
|
68585-34-2
|
Sodium xylenesulphonate
|
1 - 15
|
1300-72-7
|
2-Butoxyethanol
|
0.1 - 1
|
111-76-2
|
Edetic acid
|
0.1 - 1
|
60-00-4
|
Any concentration shown as a
range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within
the current knowledge of the supplier
and in the concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational
exposure limits, if available, are listed in Section 8.
Section 4. First aid
measures Description of necessary first aid measures
Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention.
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Skin contact: Flush contaminated skin with plenty of water. Continue to rinse for at least 20 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion:Wash out mouth with water. If
material has been swallowed and the exposed person is conscious, give small
quantities of water to drink. Stop if the exposed person feels sick as vomiting
may be dangerous. Do not induce vomiting unless directed to do so by medical
personnel. If vomiting occurs, the head should be kept low so that vomit does
not enter the lungs. Never give anything by mouth to an unconscious person. Get
medical attention if symptoms occur.
Most important
symptoms/effects, acute and delayed Potential acute health effects
Eye contact :
Causes
serious eye irritation.
Inhalation :
No known
significant effects or critical hazards.
Skin contact : Causes skin irritation.
Ingestion :
Irritating
to mouth, throat and stomach.
Over-exposure signs/symptomsEye contact :
Adverse symptoms may include the following: pain or irritation watering rednessInhalation: No known significant effects or critical hazards.
Skin Contact : Adverse symptoms may include the following: irritation, rednessIngestion: No known significant effects or critical hazards.Indication of immediate medical attention and special
treatment needed, if necessary
Notes to physician : In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under
medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken
involving any personal risk or without suitable training. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation.
See
toxicological information (Section 11)
Section 5. Fire-fighting
measures
Extinguishing media
Suitable extinguishing media: Use an extinguishing agent suitable for the surrounding fire.
Unsuitable
extinguishing media: None known.
Specific
hazards arising from the chemical: No specific fire or explosion hazard.
Hazardous thermal decomposition products: Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides Sulfur oxides phosphorus oxides metal oxide/oxides
Special
protective actions for fire-fighters: No special measures are required.
Special protective equipment for fire-fighters: Fire-fighters
should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Personal precautions, protective equipment and emergency
procedures
For non-emergency personnel: Do
not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency
responders : If specialized clothing is required to deal with the
spillage, take note of any information in Section 8 on suitable and unsuitable
materials. See also the information in "For non- emergency personnel".
Environmental precautions: Avoid
dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
Spill: Stop
leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry
into sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage
with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Dispose of via a licensed waste disposal
contractor. Contaminated absorbent material may pose the same hazard as the
spilled product. Note: see Section 1 for emergency
contact information and Section 13 for waste disposal.
Section 7. Handling and
storage
Precautions
for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.Advice on general occupational hygiene: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures.Conditions for safe storage including any incompatibilities: Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
Section 8. Exposure
controls/personal protection
Control parameters Occupational exposure
limits
|
| |
|
Ingredient
name
|
Exposure
limits
|
2-Butoxyethanol
|
ACGIH TLV
(United States, 6/2013).
TWA: 20 ppm
8 hours.
NIOSH REL (United States,
4/2013). Absorbed through skin.
TWA: 24
mg/m³ 10 hours.
TWA: 5 ppm 10 hours.
OSHA PEL (United States,
2/2013). Absorbed through skin.
TWA: 240
mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
|
|
|
|
|
|
Appropriate engineering controls: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Environmental exposure controls: Emissions
from ventilation or work process equipment should be checked to ensure they
comply with the requirements of environmental protection legislation.
Individual
protection measures Hygiene measures :Wash hands, forearms and face
thoroughly after handling chemical products, before eating, smoking and using
the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.Skin
protectionHand protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.Other skin protection : Appropriate footwear and
any additional skin protection measures should be selected based on the task being performed and the risks
involved and should
be approved by a
specialist before handling this product.
Respiratory protection :Use a properly fitted,
air-purifying or supplied air respirator complying with an approved standard if
a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and
the safe working limits of the selected respirator.
Section 9.
Physical and chemical properties
Appearance Physical state: Liquid. [Thin Bodied.]
Color: Green. Odor: Lemon.
Odor threshold: Not available. pH: 8-10.5
Melting point: Not available.
Boiling point : Not available. Flash point: Not available. Evaporation rate: Not available. Flammability (solid,
gas) : Not available.
Lower
and upper explosive (flammable) limits: Not available.Vapor Pressure: Not available.Vapor Density: Not available.Relative Density: Not available.
Solubility: Not available.
Partition coefficient: n- octanol/water: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature : Not available.
Viscosity : Thin Bodied.
Section 10. Stability and
reactivity
Reactivity : No
specific test data related to reactivity available for this product or its ingredients.
Chemical stability : The product is stable.
Possibility
of hazardous reactions: Under normal conditions of
storage and use, hazardous reactions will not occur.
Conditions to avoid :
No specific data.
Incompatible materials : Reactive or incompatible with the following
materials: oxidizing materials and acids.
Hazardous decomposition products: Under
normal conditions of storage and use, hazardous decomposition products should
not be produced.
Section 11. Toxicological
information
Information on
toxicological effects Acute toxicity
Product/ingredient
name
|
Result
|
Species
|
Dose
|
Exposure
|
Disodium metasilicate
|
LD50 Oral
|
Rat
|
1153 mg/kg
|
-
|
Alcohols, C9-11,
ethoxylated
|
LD50 Dermal
|
Rabbit
|
>2 g/kg
|
-
|
|
LD50 Oral
|
Rat
|
1378 mg/kg
|
-
|
Sodium xylenesulphonate
|
LD50 Oral
|
Rat
|
7200 mg/kg
|
-
|
2-Butoxyethanol
|
LC50 Inhalation Vapor
|
Rat
|
450 ppm
|
4 hours
|
|
LD50 Dermal
|
Rabbit
|
220 mg/kg
|
-
|
|
LD50 Oral
|
Rat
|
250 mg/kg
|
-
|
Irritation/Corrosion
JR-102 Green - All Purpose Cleaner
|
Section 11.
Toxicological information
|
|
Product/ingredient
name
|
Result
|
Species
|
Score
|
Exposure
|
Observation
|
Disodium metasilicate
2-Butoxyethanol
|
Skin -
Moderate irritant Skin - Severe irritant Skin - Severe irritant Eyes -
Moderate irritant Eyes - Severe irritant Skin - Mild irritant
|
Guinea pig
Human Rabbit Rabbit Rabbit Rabbit
|
-
-
-
-
-
-
|
24 hours 250
mg
24 hours 250 mg
24 hours 250 mg
24 hours 100 mg
100 mg
500 mg
|
-
-
-
-
-
-
|
Sensitization
There is no data available.
Carcinogenicity Classification
Product/ingredient
name
|
OSHA
|
IARC
|
NTP
|
ACGIH
|
EPA
|
NIOSH
|
2-Butoxyethanol Edetic acid
|
-
-
|
3
-
|
-
-
|
A3
-
|
-
-
|
-
None.
|
Specific target organ toxicity (single
exposure)
Name
|
Category
|
Route of exposure
|
Target
organs
|
Disodium metasilicate
|
Category 3
|
Not applicable.
|
Respiratory tract irritation
|
Specific target organ toxicity (repeated exposure)
There is no data available.
Aspiration hazard
There is no data available.
Information
on the likely routes of exposure: Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation :
No known
significant effects or critical hazards.
Skin contact : Causes skin irritation.
Ingestion :
Irritating
to mouth, throat and stomach.
Symptoms related to the physical,
chemical and toxicological characteristics
Eye contact : Adverse
symptoms may include the following: pain or irritation watering
redness.
Inhalation: No known significant effects or critical hazards. Skin contact: Adverse symptoms may include the following: irritation, redness
Ingestion: No known significant effects or critical hazards.
Delayed and
immediate effects and also chronic effects from short and long term exposure Short term exposure
Potential
immediate effects: No known significant effects or
critical hazards.
Potential delayed effects :
No known
significant effects or critical hazards.
Long term exposure
Potential immediate effects: No known significant effects or
critical hazards.
Potential delayed effects :
No known
significant effects or critical hazards.
Potential chronic health effects
General :No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Section 12. Ecological
information
Numerical measures of toxicity Acute toxicity
estimates
Route
|
ATE
value
|
Oral Dermal
Inhalation (vapors)
|
20155 mg/kg
22000 mg/kg
1100 mg/L
|
Toxicity
Product/ingredient
name
|
Result
|
Species
|
Exposure
|
Disodium metasilicate
Alcohols, C9-11, ethoxylated
Alcohols, C10-16, ethoxylated, sulfates, sodium
salts
2-Butoxyethanol
Edetic acid
|
Acute EC50 33.53 mg/L Fresh water
Acute LC50 2320 ppm Fresh
water Chronic NOEC 160 mg/L Fresh water Acute EC50 5.36 mg/L Fresh water
Acute EC50 2686 µg/L Fresh
water Acute LC50 8500 µg/L Fresh
water Acute EC50 3.43
mg/L Fresh water
Acute EC50 >1000 mg/L
Fresh water Acute LC50 1000 mg/L Marine water
Acute LC50
1250000 µg/L Marine water Acute EC50 113000 µg/L Fresh water Acute LC50 59800
µg/L Fresh water
|
Crustaceans - Ceriodaphnia dubia - Neonate
Fish - Gambusia affinis - Adult
Algae - Pseudokirchneriella subcapitata Crustaceans
- Ceriodaphnia dubia - Neonate
Daphnia -
Daphnia magna - Neonate Fish - Pimephales promelas Crustaceans - Ceriodaphnia
dubia - Neonate
Daphnia - Daphnia magna
Crustaceans - Chaetogammarus marinus - Young
Fish - Menidia beryllina
Daphnia -
Daphnia magna - Neonate Fish - Pimephales promelas
|
48 hours
96 hours
72 hours
48 hours
48 hours
96 hours
48 hours
48 hours
48 hours
96 hours
48 hours
96 hours
|
Persistence and degradability
There is no data available.
Bioaccumulative potential
Product/ingredient
name
|
LogPow
|
BCF
|
Potential
|
Sodium xylenesulphonate
|
-3.12
|
-
|
low
|
2-Butoxyethanol
|
0.81
|
-
|
low
|
Edetic acid
|
-
|
1.8
|
low
|
Mobility in soil
Soil/water partition coefficient (KOC): Not available.
Other adverse
effects : No known significant effects
or critical hazards.
Section 13. Disposal
considerations
Disposal methods: The generation of waste should be
avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should comply
with the requirements of environmental protection and waste disposal
legislation and any regional local authority requirements. Dispose of surplus
and non-recyclable products via a licensed waste disposal contractor. Waste
should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Waste packaging should be recycled.
Incineration or landfill should only be considered when recycling is not
feasible. This material and its container must be disposed of in a safe way. Care
should be taken when handling empty containers that have not been cleaned or
rinsed out. Empty containers or liners may retain some product residues. Avoid
dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers.
Section 14. Transport
information
|
DOT
Classification
|
IMDG
|
IATA
|
UN
number
|
Not regulated.
|
Not regulated.
|
Not regulated.
|
UN proper shipping name
|
-
|
-
|
-
|
Transport hazard class(es)
|
-
|
-
|
-
|
Packing
group
|
-
|
-
|
-
|
Environmental hazards
|
No.
|
No.
|
No.
|
Additional information
|
-
|
-
|
-
|
AERG : Not applicable.
Special precautions for user: Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according to Annex II of MARPOL 73/78 and
the IBC Code: Not available.
U.S. Federal regulations: TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory
(TSCA 8b):
All components are listed or exempted.
Clean Water Act (CWA) 311: Pentasodium triphosphate;
Edetic acid
Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs): Not listedClean Air Act Section 602 Class I
Substances: Not listedClean Air Act Section 602 Class II
Substances: Not listedDEA List I Chemicals (Precursor Chemicals): Not listedDEA List II Chemicals (Essential Chemicals): Not listedSARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ :
Not applicable.
SARA 311/312
Classification :
Immediate
(acute) health hazard
Composition/information on ingredients
Name
|
%
|
Fire hazard
|
Sudden release of pressure
|
Reactive
|
Immediate (acute) health hazard
|
Delayed (chronic)
health hazard
|
Disodium metasilicate
Alcohols, C9-11, ethoxylated
Alcohols,
C10-16, ethoxylated, sulfates, sodium salts
Sodium xylenesulphonate
2-Butoxyethanol
Edetic acid
|
1 - 15
1 - 15
1 - 15
1 - 15
0.1 - 1
0.1 - 1
|
No.
No.
No.
No.
No.
No.
|
No.
No.
No.
No.
No.
No.
|
No.
No.
No.
No.
No.
No.
|
Yes.
Yes. Yes.
Yes. Yes. Yes.
|
No.
No.
No.
No.
No.
No.
|
SARA 313
|
Product
name
|
CAS
number
|
%
|
Form R - Reporting requirements
|
2-Butoxyethanol
|
111-76-2
|
0.1 - 1
|
Supplier
notification
|
2-Butoxyethanol
|
111-76-2
|
0.1 - 1
|
SARA 313 notifications must not
be detached from the SDS and any copying and redistribution of the SDS shall
include copying and redistribution of the notice attached to copies of the SDS
subsequently redistributed.
State regulations
Massachusetts: The
following components are listed: Pentasodium triphosphate; 2-Butoxyethanol;
Edetic acid
New York : The
following components are listed: Pentasodium triphosphate; Edetic acid
New Jersey :
The following components are listed: 2-Butoxyethanol; Edetic acid
Pennsylvania : The following components are listed: Pentasodium
triphosphate; 2-Butoxyethanol; Edetic acid
California Prop. 65No products were found.
Section 16. Other information
History
Date of issue mm/dd/yyyy: 08/15/2014 Version : 1 Revised Section(s) : Not applicable.
Prepared by : KMK Regulatory Services Inc.
Key to abbreviations :
ATE
= Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System
of Classification and Labelling of Chemicals IATA = International Air Transport
Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International
Convention for the Prevention of Pollution From Ships, 1973 as modified by the
Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
subsidiaries, assumes any liability whatsoever for the accuracy
or completeness of the information contained herein.
Final determination of suitability of any material
is the sole responsibility of the user.
All materials may present
unknown hazards and should be used
with caution. Although
certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist.
|